(S)-(+)-Solketal

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Names

[ Name ]:
(S)-(+)-Solketal

[Synonym ]:
Solketal
T5O COTJ B1 B1 D1Q &&S Form
(S)-(+)-2,3-O-Isopropylideneglycerol
(S)-(+)-2,3-O-Isopropylideneglcerol
1,3-Dioxolane-4-methanol, 2,2-dimethyl-, (S)-
S-Solketal
[(4S)-2,2-Dimethyl-1,3-dioxolan-4-yl]methanol
(S)-(+)-(2,2-Dimethyl-1,3-dioxolan-4-yl)methanol
EINECS 244-910-8
(S)-(+)-1,2-Isopropylideneglycerol
D-(+)-1,2-Isopropylideneglycerol
(S)-(+)-2,2-Dimethyl-1,3-dioxolane-4-methanol
(+)-2,3-O-Isopropylidene-sn-glycerol
D-1,2-O-isopropylidene-sn-glycerol
(S)-2,2-Dimethyl-[1,3]-dioxolan-4-yl)methanol
(S)-(2,2-dimethyl-1,3-dioxolan-4-yl)methanol
(S)-2,2-Dimethyl-1,3-dioxolane-4-methanol
4-hydroxymethyl-2,2-dimethyl-1,3-dioxolane
S-(+)-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-methanol
1,2-Isopropylidene-sn-glycerol
s-glycerol acetonide
1,3-Dioxolane-4-methanol, 2,2-dimethyl-, (4S)-
MFCD00063239

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
188.5±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₆H₁₂O₃

[ Molecular Weight ]:
132.16

[ Flash Point ]:
80.0±0.0 °C

[ Exact Mass ]:
132.078644

[ PSA ]:
38.69000

[ LogP ]:
0.06

[ Vapour Pressure ]:
0.2±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.424

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S24/25

[ WGK Germany ]:
3

[ RTECS ]:
JI0400000

[ HS Code ]:
29329970

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1,2:5,6-Bis-O-(1-methylethylidene)-D-mannitol
(s)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane
(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde
acetic acid,[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]methanol
benzoic acid,[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]methanol
1,3-Dioxolane, 4-(1-bromoethenyl)-2,2-dimethyl-, (4R)
Solketal

DownStream

(4S)-2,2-dimethyl-4-(octadecoxymethyl)-1,3-dioxolane
(R)-(+)-4-Chloromethyl-2,2-Dimethyl-1,3-Dioxolane
Dibenzyl ether
[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl 4-methylbenzenesulfonate
MONOPALMITIN
(R)-(+)-2,2-DIMETHYL-1,3-DIOXOLANE-4-CARBOXYLIC ACID METHYL ESTER
(S)-ETHYL-4,5-ISOPROPYLIDENE-2-PENTANOATE
(z)-ethyl-4,5-o-isopropylidene-(s)-4,5-dihydroxy-2-pentenoate
(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde
((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate

Preparation

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

In vitro toxicities of experimental jet fuel system ice-inhibiting agents.

Sci. Total Environ. 274(1-3) , 209-18, (2001)

One research emphasis within the Department of Defense has been to seek the replacement of operational compounds with alternatives that pose less potential risk to human and ecological systems. Altern...

Effects of glycerol acetonide on adrenergic neurotransmission in isolated rabbit heart.

Arzneimittelforschung 42(11) , 1288-91, (1992)

In the present investigation, the solvent glycerol acetonide (GA, CAS 100-79-8) was added (110 mg/min) to the Tyrode buffer perfusing an isolated rabbit heart preloaded with 14C-noradrenaline (NA). GA...

Fourier transform near-infrared vibrational circular dichroism used for on-line monitoring the epimerization of 2,2-dimethyl-1,3-dioxolane-4-methanol: A pseudo racemization reaction.

Chirality 18(10) , 775-82, (2006)

Near-infrared (near-IR) Fourier transform vibrational circular dichroism (FT-VCD) spectroscopy has been used to monitor the epimerization of (S)-(+)-2,2-dimethyl-1,3-dioxolane-4-methanol (S-DDM). The ...