1-(Benzyloxy)acetone

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Names

[ CAS No. ]:
22539-93-1

[ Name ]:
1-(Benzyloxy)acetone

[Synonym ]:
1-Benzyloxy-2-propanone
Benzyl-Oxyacetone
1-(Benzyloxy)acetone
3-benzyloxypropan-2-one
2-Propanone, 1-(phenylmethoxy)-
MFCD01863536

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
268.4±15.0 °C at 760 mmHg

[ Molecular Formula ]:
C10H12O2

[ Molecular Weight ]:
164.201

[ Flash Point ]:
116.0±13.9 °C

[ Exact Mass ]:
164.083725

[ PSA ]:
26.30000

[ LogP ]:
1.63

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.502

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2914509090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • [(Allyloxy)methyl]benzene
  • [(2-Propyn-1-yloxy)methyl]benzene
  • 1-Benzyloxy-2-propanol
  • Ethyl 4-(benzyloxy)-3-oxobutanoate
  • p-Toluenesulfonic acid
  • 2-(phenylmethoxy)-1-propanol
  • Benzyl alcohol
  • 2-methylprop-2-enoxymethylbenzene
  • Benzyl chloride
  • 2-(Benzyloxy)acetonitrile

DownStream

  • 1-Benzyloxy-2-propanol
  • (2R)-1-(benzyloxy)propan-2-ol
  • 1-(BENZYLOXY)-2-METHYLPROPAN-2-OL
  • ethyl 3-methyl-4-phenylmethoxybut-2-enoate

Customs

[ HS Code ]: 2914509090

[ Summary ]:
HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Cis selective wittig olefination of a-alkoxy ketones and its application to the stereoselective synthesis of plaunotol. Inoue S, et al.

Bull. Chem. Soc. Jpn. 63(6) , 1629-1635, (1990)

Highly selective direct aldol reaction organocatalyzed by (S)-BINAM-L-prolinamide and benzoic acid using a-chalcogen-substituted ketones as donors. Guillena G, et al.

ARKIVOC 4 , 260-269, (2007)

A stereoselective formation of (Z)-2-methyl-2-alkenol by the wittig reaction: its application to a synthesis of nerylacetone and (Z,Z)-farnesylacetone. Sato K, et al.

Chem. Lett. 10(12) , 1711-1714, (1981)


More Articles

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