trimethylsilyl isothiocyanate
Suppliers
Names
[ CAS No. ]:
2290-65-5
[ Name ]:
trimethylsilyl isothiocyanate
[Synonym ]:
EINECS 218-929-7
Isothiocyanatotrimethylsilane
Methyl 1-cyclohexene-1-carboxylate
Silane,isothiocyanatotrimethyl
MFCD00004797
Trimethylsilyl isothiocyanate
Chemical & Physical Properties
[ Density]:
0.931 g/mL at 25 °C(lit.)
[ Boiling Point ]:
143 °C(lit.)
[ Melting Point ]:
−32.8 °C(lit.)
[ Molecular Formula ]:
C4H9NSSi
[ Molecular Weight ]:
131.27100
[ Flash Point ]:
95 °F
[ Exact Mass ]:
131.02200
[ PSA ]:
44.45000
[ LogP ]:
1.92410
[ Vapour density ]:
>1 (vs air)
[ Vapour Pressure ]:
6.83mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.482(lit.)
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS06, GHS08
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H226-H301 + H311 + H331-H315-H319-H334-H335
[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338-P311
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
T: Toxic;
[ Risk Phrases ]:
10-23/24/25-36/37/38-42
[ Safety Phrases ]:
S23-S26-S36/37-S45
[ RIDADR ]:
UN 1992 3/PG 3
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ Hazard Class ]:
3
[ HS Code ]:
2931900090
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Org. Biomol. Chem. 1(16) , 2908-18, (2003)
Condensation of 3-(3,5-dimethylphenyl)-2-oxocyclopentanecarboxamide (11) with oxalyl chloride and condensation of ethyl 2-benzylamino-5-methyl-3-phenylcyclopent-1-enecarboxylate (17a) with trimethylsi...
J. Org. Chem. 73(7) , 2518-26, (2008)
The epoxide moiety in the fullerene-mixed peroxide C60(O)(OOtBu)4 1 reacts readily with aryl isocyanates ArNCS (Ar = Ph, Naph) to form both the thiirane derivative C60(S)(OOtBu)4 and fullerene-fused t...
Anal. Biochem. 249(2) , 207-11, (1997)
A novel and efficient method to prepare amino acid thiohydantoins, which are required as reference standards for development of C-terminal protein sequencing, is reported. Amino acid thiohydantoins we...