4,7-phenanthroline

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Names

[ CAS No. ]:
230-07-9

[ Name ]:
4,7-phenanthroline

[Synonym ]:
pyridino[3,2-f]quinoline
phenanthroline
4,7-PHENANTHROLINE
p-phenanthroline
MFCD00004987
[4,7]phenanthroline

Chemical & Physical Properties

[ Density]:
1.25g/cm3

[ Boiling Point ]:
365.1ºC at 760mmHg

[ Melting Point ]:
172-174ºC(lit.)

[ Molecular Formula ]:
C12H8N2

[ Molecular Weight ]:
180.20500

[ Flash Point ]:
164.8ºC

[ Exact Mass ]:
180.06900

[ PSA ]:
25.78000

[ LogP ]:
2.78300

[ Vapour Pressure ]:
3.38E-05mmHg at 25°C

[ Index of Refraction ]:
1.74

MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H318

[ Precautionary Statements ]:
P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2933990090

Synthetic Route

Precursor & DownStream

Precursor

  • Acetamide,N-(2,3-dichlorophenyl)-
  • BENZENAMINE, 2,3-DICHLORO-4-NITRO-
  • 2,3-Dichloroaniline
  • 7,8-dichloro-6-nitroquinoline
  • Glycerol
  • p-Phenylenediamine
  • Aniline Yellow

DownStream

  • [3,3']bipyridinyl-2,2'-dicarboxylic acid
  • 1,2,3,4-tetrahydro-4,7-phenanthroline
  • 1,2,3,4,7,8,9,10-octahydro-[4,7]phenanthroline

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Cold-spray ionization mass spectrometric detection of a coordination oligomer.

Anal. Sci. 28(7) , 635-7, (2012)

Coordination polymer (CP) formation is an unexplored area in weak-interaction chemistry due to the difficulty of monitoring the coordination process. By using cold-spray ionization mass spectrometry (...

Mononucleotide recognition by cyclic trinuclear palladium(II) complexes containing 4,7-phenanthroline N,N bridges.

Dalton Trans. (10) , 1563-6, (2004)

Reaction of [(dach)Pd(NO3)2] entities (dach = (R,R)-1,2-diaminocyclohexane, (S,S)-1,2-diaminocyclohexane) and 4,7-phenanthroline (phen) providing, respectively, 90 and 120 degrees bond angles, leads t...

Reactions of phthalazine, quinazoline, 4,7-phenanthroline and 2,3'-bipyridine with ruthenium carbonyl.

Dalton Trans. 41(24) , 7249-57, (2012)

The reactions of [Ru(3)(CO)(12)] with four aromatic diazines have been studied in THF at reflux temperature. With phthalazine (L(1)), the compound [Ru(3)(μ-κ(2)N(2)N(3)-L(1))(μ-CO)(3)(CO)(7)] (1), whi...


More Articles


Related Compounds

  • 3-methyl-4,7-phenanthroline
  • 2-methyl-4,7-phenanthroline
  • 1-methyl-4,7-phenanthroline
  • 5-chloro-4,7-phenanthroline
  • 4,7-Phenanthroline-5,6-dione
  • 5-Methoxy-4,7-phenanthroline