Dimethyl Trithiocarbonate

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Names

[ Name ]:
Dimethyl Trithiocarbonate

[Synonym ]:
Carbonotrithioic acid,dimethyl ester
Carbonotrithioic acid, dimethyl ester
Dimethyl carbonotrithioate
S,S-dimethyl trithiocarbonate
Trithiocarbonic acid dimethyl ester
Dimethyl trithiocarbonate
Carbonotrithioic acid, dimethyl ester (9CI)
CARBONIC ACID,TRITHIO-,DIMETHYL ESTER
MFCD00040235

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
256.2±7.0 °C at 760 mmHg

[ Melting Point ]:
-3ºC(lit.)

[ Molecular Formula ]:
C₃H₆S₃

[ Molecular Weight ]:
138.275

[ Flash Point ]:
108.7±18.2 °C

[ Exact Mass ]:
137.963165

[ PSA ]:
82.69000

[ LogP ]:
2.12

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.625

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ RIDADR ]:
UN3334 9

[ WGK Germany ]:
3

[ RTECS ]:
FG2975000

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Carbon disulphide
methyl iodide
Disodium carbonotrithioate
Acetone
Methyl p-toluenesulfonate
Methylisocyanate 1 x 500mg neat
Dimethyl sulfate
Carbonotrithioic acid,dipotassium salt (9CI)

DownStream

Thiocarbanilide
3-PHENYL-2-THIOXO-1,2,3,4-TETRAHYDROQUINAZOLIN-4-ONE
tris(methylthio)methane
Tetrakis(methylthio)ethylene
1,1,1,2,2,2-hexakis(methylsulfanyl)ethane
Carbamodithioic acid,methyl-, methyl ester (9CI)
Crystal Violet
3-(4-BROMOPHENYL)-2-THIOXO-2,3-DIHYDROQUINAZOLIN-4(1H)-ONE
Trimethylsulfonium iodide
1,1-Diphenyl-2-thiourea

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

The 13C chemical shift tensor principal values and orientations in dialkyl carbonates and trithiocarbonates.

Solid State Nucl. Magn. Reson. 22(4) , 439-57, (2002)

The 13C chemical shift tensor principal values for the trigonal carbonate and thiocarbonate carbon atoms in the dialkyl carbonates, dimethyl carbonate, ethylene carbonate, and diphenyl carbonate, and ...

A New Application of Dimethyl Trithiocarbonate. Methylthiothiocarbonylation of 2, 4-Pentanedione and Some β-Oxoesters. Oliva A, et al.

Synth. Commun. 28(18) , 3381-86, (1998)

Gas-Phase Thermolysis, 14. On the Isomerization of Dimethyl Carbonate and Its Mono-, Di-, and Trithio Analogs. Egsgaard H, et al.

Chem. Ber. 124(5) , 1265-1270., (1999)