tetraphenylphosphine imide

Names

[ Name ]:
tetraphenylphosphine imide

[Synonym ]:
MFCD00003044
Anilidenetriphenylphosphorane
EINECS 219-039-1
Tetraphenylphosphinimine
Phosphine imide,tetraphenyl
Tetraphenylphosphine imide

Chemical & Physical Properties

[ Density]:
1.07g/cm3

[ Boiling Point ]:
505.3ºC at 760mmHg

[ Melting Point ]:
130ºC

[ Molecular Formula ]:
C₂₄H₂₀NP

[ Molecular Weight ]:
353.39600

[ Flash Point ]:
259.4ºC

[ Exact Mass ]:
353.13300

[ PSA ]:
22.17000

[ LogP ]:
5.49580

[ Vapour Pressure ]:
7.78E-10mmHg at 25°C

[ Index of Refraction ]:
1.6

[ Water Solubility ]:
chloroform: soluble25mg/mL, clear to slightly hazy (colorless to brown) | Insoluble in water. Soluble in chloroform 25 mg/mL.

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Triphenylphosphine
Benzene, azido-
triphenyldibromophosphorane
anilinotriphenylphosphomium bromide
2-azido-1,3,5-trimethylbenzene
1,2-diphenyldiazene
bromotriphenylphosphonium bromide
Diethyl ether

DownStream

1H-Isoindol-1-one,2,3-dihydro-2-phenyl-
(Hydroxy-3-dihydro-1,3-isobenzofuranyl-1)-3-phenyl-2-isoindoline-one-1
N-(4-Methoxybenzyl)aniline
N-n-Hexylaniline
(N-methyl-n-phenylamino)triphenylphosphonium iodide
1,1,1,3,3,3-hexafluoro-N-phenylpropan-2-imine
6-phenyl-6-azabicyclo[3.1.0]hexane
trans,trans-dibenzalacetone
Phenyl isothiocyanate
Triphenylphosphine sulfide

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

N-(triphenylphosphoranylidene) aniline as a novel electrolyte additive for high voltage LiCoO₂ operations in lithium ion batteries. Lee J-N, et al.

Electrochim. Acta 56(14) , 5195-5200, (2011)

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Methanesulphonyl trifluorometanesulphonyl imide, sodium salt
N-methylcamphor-imide
4-(1H-Imidazol-1-yl)-1H-pyrazole
[2-(1,1-Difluoroethyl)-4-fluorophenyl]boronic acid
3-(3-Tert-butylphenyl)benzaldehyde
(E)-N'-(4-(Difluoromethyl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl)-N,N-dimethylformimidamide
3-Cyclopropyl-5-(hydroxymethyl)benzaldehyde
Methyl 3-(difluoromethoxy)-5-formylbenzoate
tert-Butyl 3-((4-bromo-2-methoxyphenoxy)methyl)azetidine-1-carboxylate
(3-Fluoro-4-nitrophenyl)(3-methoxyazetidin-1-yl)methanone
N-(2-Fluorophenyl)-5,6,7,8-tetrahydroquinazoline-4-carboxamide
(2R)-tert-butyl 2-(hydroxymethyl)-4-methoxy-4-methylpyrrolidine-1-carboxylate

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