Trimethylsilyl acetate

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Names

[ Name ]:
Trimethylsilyl acetate

[Synonym ]:
MFCD00042651
Trimethylsilylacetic acid
trimethylsilanyl-acetic acid
Silanol, 1,1,1-trimethyl-, acetate
2-(Trimethylsilyl)ethansaeure
(trimethylsilyl)-aceticaci
Acetic acid, trimethylsilyl ester
Silanol, trimethyl-, acetate
2-(Trimethylsilyl)acetic acid
EINECS 219-067-4
Trimethylsilyl acetate
me3SiCH2cox

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
107.5±0.0 °C at 760 mmHg

[ Melting Point ]:
39-42 °C(lit.)

[ Molecular Formula ]:
C₅H₁₂O₂Si

[ Molecular Weight ]:
132.233

[ Flash Point ]:
4.4±0.0 °C

[ Exact Mass ]:
132.060654

[ PSA ]:
37.30000

[ LogP ]:
1.24

[ Vapour Pressure ]:
27.0±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.391

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN3261

[ WGK Germany ]:
2

[ RTECS ]:
AK0843500

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

P.A. Grieco et al.

J. Chem. Soc. Chem. Commun. , 537, (1975)

D.H. Lucast, J. Wemple

Tetrahedron Lett. , 1103, (1977)

G.A. Olah et al.

Synthesis , 568, (1989)

Trimethylsilyl acetate
Ethyl trimethylsilyl acetate
trimethylsilyl acetate phenylhydrazone
ethyl 2,2-difluoro-2-trimethylsilyl acetate
methyl tributylstannyltrimethylsilyl acetate
Ethyl (trimethylsilyl)acetate
1-Bromo-2-fluoro-4-(2-isocyanatoethyl)benzene
(2S)-1-amino-4-(1H-1,2,3,4-tetrazol-1-yl)butan-2-ol
(1,4-dimethyl-1H-pyrazol-3-yl)methanethiol
[4,4-Difluoro-1-(2-methyl-5-nitrophenyl)cyclohexyl]methanamine
5-(1-{[(Tert-butoxy)carbonyl](methyl)amino}ethyl)-1,2-oxazole-3-carboxylic acid
4-(5-chlorofuran-2-yl)-1H-imidazole
3-(3-Chloro-4-fluorophenyl)-2-hydroxy-2-methylpropanoic acid
2-(1-Propylcyclobutyl)acetic acid
1-methyl-1H-indazole-3-sulfonyl fluoride
3-{Pyrazolo[1,5-a]pyrimidin-2-yl}butan-1-amine

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