2-Fluoro-3-methylpyridine

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Names

[ CAS No. ]:
2369-18-8

[ Name ]:
2-Fluoro-3-methylpyridine

[Synonym ]:
2-fluor-3-methylpyridin
Pyridine, 2-fluoro-3-methyl-
2-Fluoro-3-Methyl Pyridine
2-Fluoro-3-methylpyridine
MFCD00041223
2-Fluoro-3-picoline

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
156.0±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C6H6FN

[ Molecular Weight ]:
111.117

[ Flash Point ]:
48.2±21.8 °C

[ Exact Mass ]:
111.048424

[ PSA ]:
12.89000

[ LogP ]:
1.30

[ Vapour Pressure ]:
3.8±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.477

[ Storage condition ]:
Flammables area

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R10;R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S36-S36/37/39-S16-S16 26 36/37/39

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Hazard Class ]:
3.0

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3-Methylpyridin-2-amine
  • 3-Mepy
  • Acetonitrile

DownStream

  • 2-(4-fluorophenyl)-3-methylpyridine
  • 2-Phenylnicotinic acid
  • 3-Pyridinecarboxamide,2-fluoro-
  • 2-Fluoronicotinic acid
  • 2-Fluoro-3-formylpyridine
  • 2-Methoxy-3-methylpyridine
  • 5H-Indeno[1,2-b]pyridine
  • 3-(Bromomethyl)-2-fluoropyridine
  • 2-(4-chlorophenyl)pyridine-3-carboxylic acid
  • 2-(4-FLUOROPHENYL)NICOTINIC ACID

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

A facile synthesis of 7-halo-5H-indeno [1, 2-b] pyridines and-pyridin-5-ones. DuPriest MT, et al.

J. Org. Chem. 51(11) , 2021-23, (1986)

Synthesis of 2-and 6-fluoronicotinamides. Minor JT, et al.

J. Am. Chem. Soc. 71(3) , 1125-1126, (1949)

Signs of proton-proton and proton-fluorine spin-spin coupling constants in 2-fluoro-3-methylpyridine. Sigma and pi contributions to coupling in a nitrogen heterocycle. Schaefer T, et al.

Can. J. Chem. 47(9) , 1507-1514, (1969)


More Articles

Related Compounds

  • 4-Bromo-2-fluoro-3-methylpyridine
  • 5-Amino-2-fluoro-3-methylpyridine
  • 5-bromo-2-fluoro-3-methylpyridine
  • 5-Cyano-2-fluoro-3-methylpyridine
  • 6-Bromo-2-fluoro-3-methylpyridine
  • 5-Chloro-2-fluoro-3-methylpyridine
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • Acetyl flavone
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 2,4,6-trimethyl-N-(2-(2-(p-tolyl)thiazolo[3,2-b][1,2,4]triazol-6-yl)ethyl)benzenesulfonamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine