7-chloro-4-hydrazinoquinoline

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Names

[ CAS No. ]:
23834-14-2

[ Name ]:
7-chloro-4-hydrazinoquinoline

[Synonym ]:
7-Chloro-4-hydrazinoquinoline
7-chloro-4-hydrazinylquinoline
QUINOLINE,7-CHLORO-4-HYDRAZINO
4-amino-7-chloroquinoline
4-Hydrazino-7-chloroquinoline
7-chloro-4-quinolylhydrazine
MFCD00006776

Chemical & Physical Properties

[ Density]:
1.43g/cm3

[ Boiling Point ]:
413.5ºC at 760mmHg

[ Melting Point ]:
219-225 °C (dec.)(lit.)

[ Molecular Formula ]:
C9H8ClN3

[ Molecular Weight ]:
193.63300

[ Flash Point ]:
203.8ºC

[ Exact Mass ]:
193.04100

[ PSA ]:
50.94000

[ LogP ]:
2.94710

[ Vapour Pressure ]:
4.8E-07mmHg at 25°C

[ Index of Refraction ]:
1.758

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VB2900000
CHEMICAL NAME :
Quinoline, 7-chloro-4-hydrazino-
CAS REGISTRY NUMBER :
23834-14-2
BEILSTEIN REFERENCE NO. :
0141468
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C9-H8-Cl-N3
MOLECULAR WEIGHT :
193.65
WISWESSER LINE NOTATION :
T66 BNJ EMZ IG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
40 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JMCMAR Journal of Medicinal Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC 20037) V.6- 1963- Volume(issue)/page/year: 12,801,1969

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . R36/37/38:Irritating to eyes, respiratory system and skin .

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
VB2900000

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4,7-Dichloroquinoline

DownStream

  • 7-Chloro-4-quinolinamine
  • (7-chloroquinolin-4-yl)imino-imino-azanium

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Synthesis, magnetic, spectral, and antimicrobial studies of Cu(II), Ni(II) Co(II), Fe(III), and UO2(II) complexes of a new Schiff base hydrazone derived from 7-chloro-4-hydrazinoquinoline.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 66(1) , 28-36, (2007)

A new hydrazone ligand, HL, was prepared by the reaction of 7-chloro-4-hydrazinoquinoline with o-hydroxybenzaldehyde. The ligand behaves as monoprotic bidentate. This was accounted for as the ligand c...

Synthesis and antitubercular activity of heteroaromatic isonicotinoyl and 7-chloro-4-quinolinyl hydrazone derivatives.

ScientificWorldJournal 10 , 1347-55, (2010)

Two series of N'-(E)-heteroaromatic-isonicotinohydrazide derivatives (3a-f and 4a-b) and 1-(7-chloroquinolin-4-yl)-2-[(heteroaromatic)methylene]hydrazone derivatives (5a-f and 6a-b) have been synthesi...


More Articles

Related Compounds

  • 7-CHLORO-4-HYDRAZINOQUINOLINE HYDROCHLORIDE
  • 7-Chloro-2,8-dimethyl-4-hydrazinoquinoline hydrochloride
  • 7-Chloro-4-phenylfuro[2,3-d]pyridazine
  • 7-Chloro-4-(dimethylamino)-1,4,4a,5,5a,6,11,12a-octahydro-3,6,9,10,12,12a-hexahydroxy-1,11-dioxo-2-naphthacenecarboxamide
  • 7-CHLORO-4-METHOXY-QUINOLINE-3-CARBOXYLIC ACID
  • [(7-chloro-4-thia-1,6-diazabicyclo[3.3.0]octa-2,5,7-trien-8-yl)methylideneamino]thiourea
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • ethyl (3-(furan-2-yl)-1-(2-hydroxyethyl)-1H-pyrazol-5-yl)carbamate
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide