1,2-Ethanedione,1,2-diphenyl-, 1,2-dioxime

Suppliers

Names

[ CAS No. ]:
23873-81-6

[ Name ]:
1,2-Ethanedione,1,2-diphenyl-, 1,2-dioxime

[Synonym ]:
dibenzoyldioxime
(1E,2E)-Benzil dioxime
Diphenylgyoxime
dioxime
diphenyl-glyoxim
1,2diphenylethanedione dioxime
diphenylethanedionedioxime
EINECS 245-921-0
BIBENZOYL DIOXIME
A-BENZIL DIOXIME
Benzil Dioxime
1,2-diphenylethane-1,2-dione dioxime
MFCD00002113

Chemical & Physical Properties

[ Density]:
1.17 g/cm3

[ Boiling Point ]:
393.3ºC at 760 mmHg

[ Melting Point ]:
237-240 °C (dec.)(lit.)

[ Molecular Formula ]:
C14H12N2O2

[ Molecular Weight ]:
240.25700

[ Flash Point ]:
191.7ºC

[ Exact Mass ]:
240.09000

[ PSA ]:
65.18000

[ LogP ]:
2.74340

[ Vapour Pressure ]:
0mmHg at 25°C

[ Index of Refraction ]:
1.596

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DD1985000
CHEMICAL NAME :
Benzil, dioxime
CAS REGISTRY NUMBER :
23873-81-6
BEILSTEIN REFERENCE NO. :
2053615
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C14-H12-N2-O2
MOLECULAR WEIGHT :
240.28
WISWESSER LINE NOTATION :
QNUYR&YR&UNQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PCJOAU Pharmaceutical Chemistry Journal (English Translation). Translation of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No.1- 1967- Volume(issue)/page/year: 12,227,1978

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
DD1985000

[ HS Code ]:
2928000090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Benzil
  • Z-ALPHA,BETA-DINITROSTILBENE
  • 2,3-diphenylthiirene 1-oxide

DownStream

  • meso-1,2-Diphenylethylenediamine
  • (1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine
  • (1R,2R)-(+)-1,2-Diphenylethylenediamine
  • sodium chloride
  • 3,4-diphenyl-1,2,5-oxadiazole
  • 1,2,4-Oxadiazole,3,5-diphenyl-

Customs

[ HS Code ]: 2928000090

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Determination of cobalt in vegetable animal foodstuffs by differential pulse adsorptive voltammetry using alpha-benzil dioxime.

Sci. Total Environ. 176(1-3) , 135-9, (1995)

A selective and sensitive voltammetric method for the determination of cobalt in vegetable animal foodstuffs is developed. The method is based on the use of alpha-benzil dioxime (alpha-BD) as a chelat...

Selective and sensitized spectrophotometric determination of trace amounts of Ni(II) ion using alpha-benzyl dioxime in surfactant media.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 66(2) , 295-301, (2007)

Highly sensitive and interference-free sensitized spectrophotometric method for the determination of Ni(II) ions is described. The method is based on the reaction between Ni(II) ion and benzyl dioxime...


More Articles

Related Compounds

  • 1,2-Ethanedione,1,2-diphenyl-, 1,2-bis(2-phenylhydrazone)
  • 1,2-Ethanedione,1,2-diphenyl-, 1,2-dihydrazone
  • 1,2-Ethanedione,1,2-diphenyl-, 1-(2-phenylhydrazone)
  • 1,2-Ethanedione,1,2-diphenyl-, 1-oxime
  • 1,2-Ethanedione,1,2-diphenyl-, 1-hydrazone
  • Benzil
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine