PhDavePhos

Suppliers

Names

[ Name ]:
PhDavePhos

[Synonym ]:
2'-(Diphenylphosphino)-N,N-dimethyl-2-biphenylamine
2′-(Diphenylphosphino)-N,N′-dimethyl-(1,1′-biphenyl)-2-amine
PhDave-Phos
2'-(diphenylphosphino)-N,N-dimethyl-[1,1'-biphenyl]-2-amine
2'-(Diphenylphosphino)-N,N-dimethylbiphenyl-2-amine
[1,1'-Biphenyl]-2-amine, 2'-(diphenylphosphino)-N,N-dimethyl-
2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl
MFCD03094578
RW2172
2-Diphenylphosphino-2`-dimethylaminobiphenyl
2-Ph2P-2'-(Me2N)biphenyl
PhDavePhos
2-Diphenylphosphino-2‘-(N,N-dimethylamino)biphenyl
2-Dimethylamino-2'-(diphenylphosphino)biphenyl
2-Diphenylphosphino-2'-(N,N-dimethyl amino)biphenyl

Chemical & Physical Properties

[ Boiling Point ]:
514.6±43.0 °C at 760 mmHg

[ Melting Point ]:
126-128 °C

[ Molecular Formula ]:
C₂₆H₂₄NP

[ Molecular Weight ]:
381.449

[ Flash Point ]:
265.0±28.2 °C

[ Exact Mass ]:
381.164642

[ PSA ]:
16.83000

[ LogP ]:
7.56

[ Vapour Pressure ]:
0.0±1.3 mmHg at 25°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
37/39-26-36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
NM1880000

[ HS Code ]:
2921499090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

potassium diphenylphosphide
(2'-(dimethylamino)biphenyl-2-yl)diphenylphosphine oxide
1-Bromo-2-iodobenzene
1-bromo-2-diphenylphosphorylbenzene
Diphenylphosphine oxide
Diphenylphosphine
(2-Bromophenyl)(diphenyl)phosphine

DownStream

Customs

[ HS Code ]: 2921499090

[ Summary ]:
2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

Acc. Chem. Res. 41 , 1461, (2008)

The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia...

Biaryl phosphane ligands in palladium-catalyzed amination.

Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008)

Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr...

Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.

Chem. Sci. 2 , 27, (2011)

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th...