Methyl 4-(bromomethyl)benzoate

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Names

[ Name ]:
Methyl 4-(bromomethyl)benzoate

[Synonym ]:
Methyl-4-(brommethyl)benzolcarboxylat
methyl4-(bromomethyl)benzoate
Benzoic acid, 4-(bromomethyl)-, methyl ester
4-methoxycarbonylbenzyl bromide
4-(Bromomethyl)benzoic Acid Methyl Ester
4-Bromomethyl benzoic acid methyl ester
Methyl 4-(bromomethyl)benzoate
α-Bromo-p-toluic Acid Methyl Ester
Methyl 4-bromomethylbenzoate
4-Bromomethylbenzoic acid methyl ester
MFCD00032453
Methyl α-Bromo-p-toluate

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
309.7±0.0 °C at 760 mmHg

[ Melting Point ]:
57-58 °C(lit.)

[ Molecular Formula ]:
C₉H₉BrO₂

[ Molecular Weight ]:
229.071

[ Flash Point ]:
127.8±22.6 °C

[ Exact Mass ]:
227.978592

[ PSA ]:
26.30000

[ LogP ]:
2.90

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.560

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H314-H334

[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S25

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

methyl p-toluate
diazomethane
4-Bromomethylbenzoic acid
Methanol
Methyl (4-hydroxymethyl)benzoate
4-bromomethyl benzoyl chloride
Benzoyl peroxide
Methyl 4-formylbenzoate
Chlorobenzene
Tetrabromomethane

DownStream

methyl 4-(sulfamoylmethyl)benzoate
METHYL 4-((2-FORMYLPHENOXY)METHYL)BENZOATE
Methyl 4-(2-methoxy-2-oxoethyl)benzoate
4-(Phenoxymethyl)benzoic acid
methyl 4-[[(4-methoxycarbonylphenyl)methylamino]methyl]benzoate
Methyl 4-((Diethoxyphosphoryl)Methyl)Benzoate
methyl 4-[[4-[(4-methoxycarbonylphenyl)methylsulfanylmethyl]-2,5-dioxoimidazolidin-4-yl]methylsulfanylmethyl]benzoate
4-((1-(Tert-butoxycarbonyl)piperidin-4-yl)methyl)benzoicacid
4-(carboxymethyl)-3-nitrobenzoic acid
[4-(pyrrolidin-1-ylmethyl)phenyl]methanol

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Synthesis, characterization and potent DNA-cleaving activity of copper(II)-complexed berberine carboxylate.

Bioorg. Med. Chem. Lett. 22(23) , 7056-9, (2012)

9-O-(4-carboxybenzyl)berberine (CBB) 1 was synthesized from the reaction of berberrubine with methyl 4-(bromomethyl)benzoate and subsequent hydrolysis. Its Cu(II) complex 2 was prepared from the react...

Methyl 4-(bromomethyl) benzoate. Yathirajan HS, et al.

Acta Crystallogr. Sect. E Struct. Rep. Online 63(3) , o1334-5, (2007)

methyl 4-(bromomethyl)-3-(trifluoromethyl)benzoate
methyl-4-bromomethyl-2,6-dimethoxy benzoate
Methyl 4-bromomethyl-3-cyanobenzoate
Methyl 4-(bromomethyl)-2-fluoro-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate
methyl 4-(bromomethyl)-2,3-difluorobenzoate
Methyl 4-(bromomethyl)-2,6-difluorobenzoate
1-[4-(Difluoromethoxy)-2-fluorophenyl]-3-oxocyclobutane-1-carboxylic acid
tert-butyl N-{5-[1-(aminomethyl)-4-hydroxycyclohexyl]-2-methylphenyl}carbamate
Tert-butyl 2-(1-amino-3-hydroxypropyl)-5,5-dimethylpiperidine-1-carboxylate
3,3-Difluoro-3-(4-methyl-3-nitrophenyl)propanoic acid
2-[1-(2,3-dihydro-1H-inden-1-yl)cyclobutyl]ethan-1-amine
tert-butyl N-[2-amino-3-(1-methylcyclopropyl)propyl]carbamate
tert-butyl N-[2-(3-methanesulfonylphenyl)-1-oxopropan-2-yl]-N-methylcarbamate
(1R)-1-[3-(4-fluorophenyl)-1H-pyrazol-4-yl]ethan-1-amine
2-(3,5-Dichloropyridin-4-yl)ethane-1-thiol
5-(Isocyanatomethyl)-2-methoxy-3-methylpyridine