H-Phe(4-Br)-OH

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Names

[ CAS No. ]:
24250-84-8

[ Name ]:
H-Phe(4-Br)-OH

[Synonym ]:
(S)-β-(p-Bromophenyl)alanine
H-PHE(4-BR)-OH
H-PHE(P-BR)-OH
para-bromo-L-phenylalanine
p-Bromo-L-phenylalanine
L-4-BROMOPHE
L-4-Bromo-phe-OH
H-P-BROMO-PHE-OH
4-Bromophenylalanine
p-Bromophenylalanine
L-4-Bromophenylalanine
(S)-4-Bromophenylalanine
4-Bromo-L-Phenylalanine
4-Bromo-L-Phe-OH
L-PHE(4-BR)
MFCD00063062
L-4-BR-PHE
Phenylalanine, 4-bromo-
L-p-Bromophenylalanine
(S)-2-Amino-3-(4-bromophenyl)propanoic acid
H-L-PHE(4-BR)-OH
(2S)-2-amino-3-(4-bromophenyl)propanoic acid
L-4-Bromo-Phenylalanine
L-4-BR-Phe-OH
(L)-(-)-4-bromophenylalanine

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
368.4±32.0 °C at 760 mmHg

[ Melting Point ]:
265ºC (dec.)

[ Molecular Formula ]:
C9H10BrNO2

[ Molecular Weight ]:
244.085

[ Flash Point ]:
176.6±25.1 °C

[ Exact Mass ]:
242.989487

[ PSA ]:
63.32000

[ LogP ]:
1.88

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.609

[ Storage condition ]:
Store at RT.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301

[ Precautionary Statements ]:
P301 + P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic

[ Risk Phrases ]:
R25

[ Safety Phrases ]:
S45

[ RIDADR ]:
UN2811

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2922499990

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Bromo-L-Phe-OH
  • L-Phenylalanine
  • tert-butyl (2S,5S)-5-(4-bromobenzyl)-2-(tert-butyl)-3-methyl-4-oxo-1-imidazolidinecarboxylate
  • 4-Bromobenzyl bromide
  • 4-Bromocinnamic acid

DownStream

  • TR 14035
  • (S)-N-Boc-4-Bromophenylalanine
  • boc-l-4-br-phe-nitrile

Customs

[ HS Code ]: 2922499990

[ Summary ]:
HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%

Articles

Efficient introduction of aryl bromide functionality into proteins in vivo.

FEBS Lett. 467(1) , 37-40, (2000)

Artificial proteins can be engineered to exhibit interesting solid state, liquid crystal or interfacial properties and may ultimately serve as important alternatives to conventional polymeric material...

Relaxing the substrate specificity of an aminoacyl-tRNA synthetase allows in vitro and in vivo synthesis of proteins containing unnatural amino acids.

FEBS Lett. 364(3) , 272-5, (1995)

It has previously been demonstrated that the unnatural amino acid p-Cl-phenylalanine can be attached to tRNA(Phe) by a modified phenylalanyl-tRNA synthetase with relaxed amino acid substrate specifici...

Neutron capture therapy for melanoma.

Basic Life Sci. 50 , 219-32, (1989)


More Articles

Related Compounds

  • H-Phe(4-Br)-Ome.HCl
  • H-Phe(4-Br)-OMe hydrochloride
  • H-alpha-Me-D-Phe(4-Br)-OH
  • 4-Bromo-L-Phe-OH
  • 4-Bromo-D-Phe-OH
  • Ac-DL-Phe(4-Br)-OH
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[5-cyano-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pentanoyl]-2-methylpyrrolidine-3-carboxylic acid
  • tert-butyl N-[2-(4-bromophenyl)-2-methylpropyl]carbamate
  • benzyl N-[2-(2-nitrophenyl)ethyl]carbamate
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde