Butyl glycidyl ether

Suppliers

Names

[ Name ]:
Butyl glycidyl ether

[Synonym ]:
erl0810
BGE
Epirez 501
1-butoxy-2,3-epoxypropane
Heloxy 61
1,2-Epoxy-3-butoxypropane
ageflexbge
butyl 2,3-epoxypropyl ether
(Butoxymethyl)oxirane
2,3-epoxypropyl n-butyl ether
sipomerbge
MFCD00005145
2-(Butoxymethyl)oxirane
n-butyl glycidyl ether
EINECS 219-376-4
NBGE
Oxirane, 2-(butoxymethyl)-
3-n-butoxy-1,2-epoxypropane

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
177.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₇H₁₄O₂

[ Molecular Weight ]:
130.185

[ Flash Point ]:
54.4±0.0 °C

[ Exact Mass ]:
130.099380

[ PSA ]:
21.76000

[ LogP ]:
1.42

[ Vapour Pressure ]:
1.4±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.433

[ Stability ]:
Stable. May form explosive peroxides on contact with air. Store under inert gas.

[ Water Solubility ]:
2 g/100 mL

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TX4200000

CHEMICAL NAME :: Propane, 1-butoxy-2,3-epoxy-

CAS REGISTRY NUMBER :: 2426-08-6

BEILSTEIN REFERENCE NO. :: 0103668

LAST UPDATED :: 199712

DATA ITEMS CITED :: 50

MOLECULAR FORMULA :: C7-H14-O2

MOLECULAR WEIGHT :: 130.21

WISWESSER LINE NOTATION :: T3OTJ B1O4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1660 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - respiratory depression

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1030 ppm/8H

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Gastrointestinal - changes in structure or function of salivary glands Lungs, Thorax, or Respiration - dyspnea

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >2150 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1140 mg/kg

TOXIC EFFECTS :: Brain and Coverings - recordings from specific areas of CNS Behavioral - somnolence (general depressed activity) Behavioral - ataxia

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1530 mg/kg

TOXIC EFFECTS :: Brain and Coverings - recordings from specific areas of CNS Behavioral - somnolence (general depressed activity) Behavioral - ataxia

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 260 mg/m3

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - respiratory depression

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 700 mg/kg

TOXIC EFFECTS :: Brain and Coverings - recordings from specific areas of CNS Behavioral - somnolence (general depressed activity) Behavioral - ataxia

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 2520 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

DOSE :: 36 gm/kg

SEX/DURATION :: male 24 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Effects on Embryo or Fetus - fetal death

TYPE OF TEST :: Micronucleus test

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Lung

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 249,55,1991 *** REVIEWS *** ACGIH TLV-TWA 133 mg/m3 (25 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 50 ppm (270 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,33,1971 OSHA PEL (Gen Indu):8H TWA 50 ppm (270 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 50 ppm (270 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 50 ppm (270 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 50 ppm (270 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 25 ppm (135 mg/m3) JAN 1993 OEL-BELGIUM:TWA 25 ppm (133 mg/m3) JAN 1993 OEL-DENMARK:TWA 6 ppm (30 mg/m3) JAN 1993 OEL-FINLAND:STEL 25 ppm (135 mg/m3);Skin JAN 1993 OEL-FRANCE:TWA 25 ppm (135 mg/m3) JAN 1993 OEL-GERMANY;Skin;Carcinogen JAN 1993 OEL-THE NETHERLANDS:TWA 25 ppm (135 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 50 ppm (270 mg/m3) JAN 1993 OEL-SWEDEN:TWA 10 ppm (50 mg/m3);STEL 15 ppm (80 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 25 ppm (135 mg/m3);STEL 50 ppm;Skin JAN 1993 OEL-TURKEY:TWA 50 ppm (270 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 25 ppm (135 mg/m3) JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO BUTYL GLYCIDYL ETHER-air:CL 5.6 ppm/15M REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 14720 No. of Facilities: 1596 (estimated) No. of Industries: 37 No. of Occupations: 45 No. of Employees: 19839 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 14720 No. of Facilities: 2593 (estimated) No. of Industries: 56 No. of Occupations: 57 No. of Employees: 60217 (estimated) No. of Female Employees: 14929 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H302-H314-H317-H331-H335-H341-H350-H412

[ Precautionary Statements ]:
P201-P261-P273-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R10;R20/22;R37;R40;R43;R52/53;R68

[ Safety Phrases ]:
S24/25-S36/37-S61

[ RIDADR ]:
UN 3271 3/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
TX4200000

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
29109000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Allyl Butyl Ether
Epichlorohydrin
Butanol
2-Propanol,1-butoxy-3-chloro-
1-Bromobutane
(2R)-2-[(Trityloxy)methyl]oxirane
2-((Benzyloxy)methyl)oxirane

DownStream

[2-(4-bromophenyl)-2-oxoethyl]-(3-butoxy-2-hydroxypropyl)-dimethylazanium,bromide
ETHYLENE OXIDE
1-butoxy-3-phenylselanylpropan-2-ol
1-butoxy-3-(diethylamino)propan-2-ol
2-(butoxymethyl)thiirane
1-butoxy-3-methoxypropan-2-ol
1-anilino-3-butoxypropane-2-thiol
2-(butoxymethyl)-1,4,7,10,13-pentaoxacyclopentadecane
2-(butoxymethyl)-2H-furan-5-one
2-Propanone, 1-butoxy- (9CI)

Customs

[ HS Code ]: 2910900090

[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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Carbohydr. Polym. 123 , 432-42, (2015)

Fish oil-loaded microcapsules were prepared from oil-in-water emulsions using N-stearoyl O-butylglyceryl chitosan as shell material. The emulsions were prepared by both membrane and ultrasonic emulsif...

Fine Structure of the Integumentary Cuticles and Alimentary Tissues of Pycnophyid Kinorhynchs Pycnophyes oshoroensis and Kinorhynchus yushini (Kinorhyncha, Homalorhagida).

Zoolog. Sci. 32 , 389-95, (2015)

Integumentary and alimentary tissues were ultrastructurally examined in two pycnophyid kinorhynchs, Pycnophyes oshoroensis and Kinorhynchus yushini, to elucidate some aspects of their ecology. The bod...

Nanoparticles of alkylglyceryl-dextran-graft-poly(lactic acid) for drug delivery to the brain: Preparation and in vitro investigation.

Acta Biomater. 23 , 250-62, (2015)

Poly(lactic acid), which has an inherent tendency to form colloidal systems of low polydispersity, and alkylglyceryl-modified dextran - a material designed to combine the non-immunogenic and stabilisi...

n-butyl glycidyl ether
iso-butyl glycidyl ether
tert-butyl glycidyl ether
(R)-t-Butyl glycidyl ether
Guaiacol glycidyl ether
TETRAPHENYLOLETHANE GLYCIDYL ETHER
rac-(2R,3R)-3-[(1H-pyrrol-1-yl)methyl]oxolane-2-carbohydrazide
6-Amino-2-methylpyrazolo[1,5-a]pyrimidine-3-carboxamide
N-cyclopentyl-3-((5-fluoropyrimidin-2-yl)oxy)pyrrolidine-1-carboxamide
(2,6-Dimethyl-4-pyridinyl)acetic acid hydrochloride
1-(1-Methyl-1H-imidazol-2-yl)-1-phenylmethanamine dihydrochloride
2-cyano-3-(2-hydroxypyridin-4-yl)-N-propylprop-2-enamide
Acetamide, 2,2a(2)-[[10,12,22,24-tetranitro-2,8,14,20-tetraoxapentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaene-5,17-diyl]bis(oxy)]bis[N-2-benzothiazolyl-
Ethyl 5-[2-cyano-2-(propylcarbamoyl)eth-1-en-1-yl]-1,2-oxazole-3-carboxylate
1,3,7-tris(9,9-dimethylfluoren-2-yl)-9H-carbazole
5-[2-cyano-2-(propylcarbamoyl)eth-1-en-1-yl]-1-methyl-1H-pyrazole-4-carboxylic acid

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