2-CHLORO-5 5-DIMETHYL-1 3 2-DIOXAPHOSPHO

Suppliers

Names

[ Name ]:
2-CHLORO-5 5-DIMETHYL-1 3 2-DIOXAPHOSPHO

[Synonym ]:
neopentylene phosphorochloridite
5,5-dimethyl-2-chloro-1,3,2-dioxaphosphorinane
1-chloro-4,4-dimethyl-1-phospha-2,6-dioxahexane
2-Chloro-5,5-dimethyl-1,3,2-dioxaphosphorinane,AcroSeal
EINECS 219-380-6
MFCD03093988
2-Chloro-5,5-dimethyl-1,3,2-dioxaphosphorinane

Chemical & Physical Properties

[ Boiling Point ]:
164.8ºC at 760mmHg

[ Molecular Formula ]:
C₄H₈ClO₂P

[ Molecular Weight ]:
154.53200

[ Flash Point ]:
53.5ºC

[ Exact Mass ]:
153.99500

[ PSA ]:
32.05000

[ LogP ]:
2.27750

[ Vapour Pressure ]:
2.54mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.476(lit.)

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
14-34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 3094 8/PG 2

[ HS Code ]:
2934999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Neopentyl glycol
2-tert-Butyl-4-methoxyphenol

DownStream

2-bromo-5,5-dimethyl-1,3,2-dioxaphosphinane
N-ethyl-5,5-dimethyl-N-phenyl-1,3,2-dioxaphosphinan-2-amine
5 5-dimethyl-1 3 2-dioxaphosphorinan-2-&
2-ethoxy-5,5-dimethyl-1,3,2-dioxaphosphorinane
5,5-dimethyl-2-methylsulfanyl-1,3,2λ5-dioxaphosphinane 2-oxide
2-methoxy-5,5-dimethyl-2-sulfanylidene-1,3,2λ5-dioxaphosphinane
5,5-dimethyl-2-propan-2-yloxy-1,3,2-dioxaphosphinane
1,3,2-Dioxaphosphorinane,5,5-dimethyl-2-phenoxy-
N-(5,5-dimethyl-1,3,2-dioxaphosphinan-2-yl)pyridin-2-amine
5,5-dimethyl-2-propa-1,2-dienyl-1,3,2λ5-dioxaphosphinane 2-oxide

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

An improved synthesis of benzyl 3, 5-di-O-benzyl-2-deoxy-1, 4-dithio-d-erythro-pentofuranoside, an intermediate in the synthesis of 4'-thionucleosides. Dyson MR, et al.

Carbohydr. Res. 216 , 237-248, (1992)

Bis(µ-5, 5-dimethyl-1, 3, 2-dioxaphosphorinano)-diiron hexacarbonyl: a fluxional molecule exhibiting two types of proton site exchange. Bartish, Charles M., and Charles S. Kraihanzel.

Inorganic Chemistry 17(3) , 735-738, (1978)

Tungsten (Z)-1, 2-diphosphite-alkene and (E)-vinyl-phosphite complexes from phosphite Fischer carbene complexes. Barluenga J, et al.

Organometallics 16(17) , 3732-3734, (1997)

2-Chloro-5,5-dimethyl-1,3,2-dioxaphosphorinane 2-sulfide
2-chloro-5,5-dimethyl-1,3,2-dioxaphosphorinan-2-one
4-(2-chlorophenyl)-2-chloro-5,5-dimethyl-1,3,2-dioxaphosphorinan 2-oxide
2-chloro-5-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)pyridine(SALTDATA: FREE)
2-Chloro-6-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzonitrile
2-(chloro(phenyl)methyl)-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
4-(Pyrrolidin-3-ylmethoxy)benzene-1-sulfonamide
(4-Methyl-tetrahydro-furan-2-yl)-methanol
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
tert-Butyl-DL-alanine
(1-methyl-1H-pyrazol-5-yl)[4-(propan-2-yl)cyclohexyl]methanol