Diisopropyl azodicarboxylate

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Names

[ Name ]:
Diisopropyl azodicarboxylate

[Synonym ]:
diisopropyldiazodicarboxylate
Diisopropyl (E)-diazene-1,2-dicarboxylate
Diisopropyl (E)-1,2-diazenedicarboxylate
Diisopropylazodicarboxylat
EINECS 219-502-8
dipropan-2-yl (E)-diazene-1,2-dicarboxylate
DIAD
diisopropyl azodicarbonate
DIISOPYL AZODICARBOXYLATE
diazopropyl dicarboxylate
di-isopropyl azodicarboxylate
Diisopropyl Azodicarboxylate (DIAD)
1,2-Diazenedicarboxylic acid, bis(1-methylethyl) ester, (E)-
DIAD Diisopropyl azodiformate
MFCD00008875
Azodicarboxylic Acid Diisopropyl Ester
Diisopropyl diazene-1,2-dicarboxylate
Diisopropyl azodicar
Diisopropyl azodicaroxylate
diisopropyl azodiformate
Diisopropylazodicarboxylate
(E)-Diisopropyl azodicarboxylate
Diisopropyl azodicarboxylate
diisopropyl diazoacetate

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
277.0±0.0 °C at 760 mmHg

[ Melting Point ]:
3-5 °C

[ Molecular Formula ]:
C₈H₁₄N₂O₄

[ Molecular Weight ]:
202.208

[ Flash Point ]:
106.1±0.0 °C

[ Exact Mass ]:
202.095352

[ PSA ]:
77.32000

[ LogP ]:
2.54

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.475

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07, GHS08, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335-H351-H373-H411

[ Precautionary Statements ]:
P261-P273-P281-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable

[ Risk Phrases ]:
R11;R36/37/38;R43;R5;R51/53

[ Safety Phrases ]:
S36-S61-S47A-S36/37/39-S29-S26-S16-S60

[ RIDADR ]:
UN 3082 9/PG 3

[ WGK Germany ]:
1

[ Packaging Group ]:
III

[ Hazard Class ]:
9

[ HS Code ]:
29270000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

diisopropyl bicarbamate
2,6-Dichloro-4-bromophenol
Phenyl ethyl ketone
4-Bromo-2-chlorophenol
4-Bromoaniline
Benzoic anhydride
Triphenylphosphine oxide
(R)-1-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)prop-2-yn-1-yl acetate
Tributylphosphine oxide
Methyl phenylglyoxylate

Customs

[ HS Code ]: 2927000090

[ Summary ]:
2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Diels-Alder hydrogels with enhanced stability: First step toward controlled release of bevacizumab.

Eur. J. Pharm. Biopharm. 96 , 217-25, (2015)

Eight-armed PEG was functionalized with furyl and maleimide groups (8armPEG20k-Fur and 8armPEG20k-Mal); degradable hydrogels were obtained by cross-linking via Diels-Alder chemistry. To increase the s...

Molecularly imprinted polymers with synthetic dummy template for simultaneously selective removal and enrichment of ginkgolic acids from Ginkgo biloba L. leaves extracts.

J. Chromatogr. A. 1368 , 44-51, (2014)

Dummy molecularly imprinted polymers (DMIPs) for simultaneously selective removal and enrichment of ginkgolic acids (GAs) during the processing of Ginkgo biloba leaves have been prepared. Two dummy te...

One-pot synthesis of an indole-substituted 7,8-dicarba-nido-dodecahydroundecaborate(-1).

Dalton Trans. 44(4) , 1748-53, (2014)

Carbaboranes are increasingly used as pharmacophores to replace phenyl substituents in established drug molecules. In contrast to traditional organic chemistry, elaborate procedures to introduce funct...

diisopropyl azodicarboxylate-triphenylphosphine
diisopropyl(neopentyl)phosphane
Diisopropyl phosphono fluoridat
diisopropyl (1-((2,3-dihydrobenzo[b][1,4]dioxin-6-yl)amino)-1-oxopropan-2-yl)phosphonate
diisopropyl (tributylstannyl)methyl phosphate
diisopropyl 1-(hydroxyimino)ethylphosphonate