2-Ethyl-6-methylaniline

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Names

[ CAS No. ]:
24549-06-2

[ Name ]:
2-Ethyl-6-methylaniline

[Synonym ]:
EINECS 246-309-6
2-Methyl-6-ethylaniline
2-Ethyl-6-methylaniline
6-Ethyl-2-toluidine
Benzenamine,2-ethyl-6-methyl
o-Toluidine,6-ethyl
ZR B2 F1
2-ethyl-6-methyl-phenylamine
2-Ethyl-6-methylbenzenamine
6-Ethyl-o-toluidine
Aniline,2-methyl-6-ethyl
2-ethyl-5-methylphenylamine
2-Methyl-6-ethylaniline (MEA)
6-methyl-2-ethyl-aniline
Benzenamine, 2-ethyl-6-methyl-
MFCD00007752

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
228.3±9.0 °C at 760 mmHg

[ Melting Point ]:
−33 °C(lit.)

[ Molecular Formula ]:
C9H13N

[ Molecular Weight ]:
135.206

[ Flash Point ]:
89.4±0.0 °C

[ Exact Mass ]:
135.104797

[ PSA ]:
26.02000

[ LogP ]:
2.39

[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.550

[ Storage condition ]:
-20°C

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BY5600000
CHEMICAL NAME :
Aniline, 2-methyl-6-ethyl-
CAS REGISTRY NUMBER :
24549-06-2
BEILSTEIN REFERENCE NO. :
2079468
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C9-H13-N
MOLECULAR WEIGHT :
135.23
WISWESSER LINE NOTATION :
ZR B2 F1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
885 mg/kg
TOXIC EFFECTS :
Liver - other changes Blood - changes in bone marrow (not otherwise specified) Blood - changes in spleen
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2200 mg/m3/4H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - dyspnea Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
930 mg/kg
TOXIC EFFECTS :
Autonomic Nervous System - other (direct) parasympathomimetic Behavioral - muscle weakness Behavioral - ataxia
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
700 mg/kg
TOXIC EFFECTS :
Autonomic Nervous System - other (direct) parasympathomimetic Behavioral - muscle weakness Behavioral - ataxia
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2210 mg/kg/10D-C
TOXIC EFFECTS :
Blood - changes in bone marrow (not otherwise specified)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10200 mg/kg/6W-I
TOXIC EFFECTS :
Kidney, Ureter, Bladder - other changes in urine composition Blood - changes in erythrocyte (RBC) count Nutritional and Gross Metabolic - changes in chlorine

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
8300 nmol/plate
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 211,279,1988

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H331

[ Precautionary Statements ]:
P261-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S24/25-S23

[ RIDADR ]:
2810

[ WGK Germany ]:
2

[ RTECS ]:
BY5600000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2933990090

Synthetic Route

Precursor & DownStream

Precursor

  • 2-methyl-6-ethylnitrobenzene
  • 3-Ethyltoluene
  • ethene
  • o-Toluidine

DownStream

  • metolachlor [ANSI, WSSA]
  • (2-Ethyl-6-methylphenyl)diphenylamine
  • (S)-Metolachor
  • 2-ethyl-6-methylphenyl isocyanate
  • 2-ethyl-6-methylphenyl isothiocyanate
  • 3,7-Dimethyl-1H-indazole-5-carboxylic acid
  • 2-Ethyl-6-methyl-N-methylenebenzenamine
  • 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(methoxymethyl)acetamide
  • 5-Bromo-3,7-dimethyl-1H-indazole
  • 1-Ethyl-2-iodo-3-methylbenzene

Customs

[ HS Code ]: 2921493000

[ Summary ]:
HS: 2921493000. 2-ethyl-6-methylaniline. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tarrif:4.0%. general tariff:11.0%

Articles

Degradation and leaching of the herbicides metolachlor and diuron: a case study in an area of Northern Italy.

Environ. Pollut. 134(3) , 525-34, (2005)

In this work the degradation of the herbicides metolachlor, diuron, monuron and of the metabolites 2-ethyl-6-methylaniline (EMA), and 3,4-dichloroaniline (DCA) was assessed in laboratory experiments o...

Resolution of< i> N</i>-(2-ethyl-6-methylphenyl) alanine via free and immobilized lipase from< i> Pseudomonas cepacia</i>. Zheng L, et al.

J. Mol. Catal., B Enzym. 38(3) , 119-25, (2006)


More Articles


Related Compounds

  • 2-Ethyl-6-methylaniline-d13
  • 4-Bromo-2-ethyl-6-methylaniline
  • 4-chloro-2-ethyl-6-methylaniline
  • chloroacetyl-2-ethyl-6-methylaniline
  • 2-ethyl-6-methylaniline,sulfuric acid
  • N-(2-ethoxyethyl)-2-ethyl-6-methylaniline
  • Tert-butyl 2-[(azetidin-3-yl)methyl]morpholine-4-carboxylate
  • 1-(5-methyl-1H-pyrazol-3-yl)-3-oxocyclobutane-1-carboxylic acid
  • 2-Amino-3-(2-{[(tert-butoxy)carbonyl]amino}-5-chlorophenyl)propanoic acid
  • 2-Amino-1-(2,5-difluoro-4-nitrophenyl)ethan-1-one
  • Methyl 5-[1-(aminomethyl)cyclopentyl]thiophene-2-carboxylate
  • 5'-methyl-1-(propan-2-yl)-5',6'-dihydro-4'H-spiro[piperidine-4,7'-thieno[2,3-c]pyridine]
  • 1-(Pyrimidin-2-yl)-2-azabicyclo[2.2.2]octane
  • 5',6'-dihydro-4'H-spiro[bicyclo[2.2.1]heptane-2,7'-thieno[2,3-c]pyridine]
  • 6-methoxy-5',6'-dihydro-4'H-spiro[cyclohexane-1,7'-thieno[2,3-c]pyridine]
  • 7-(dimethoxymethyl)-7-methyl-4H,5H,6H,7H-thieno[2,3-c]pyridine
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