Grubbs Catalyst 2nd Generation

Suppliers

Names

[ Name ]:
Grubbs Catalyst 2nd Generation

[Synonym ]:
GRUBB'S SECOND GENERATION CATALYST
(1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium
[1,3-Bis-(2,4,6-trimethylpheny
MFCD03453237
Grubb's 2nd generation catalyst
Benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium - tricyclohexylphosphine (1:1)
Phosphine, tricyclohexyl-, compd. with [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)ruthenium (1:1)
Grubbs catalyst,2nd Generation
Grubbs 2

Chemical & Physical Properties

[ Melting Point ]:
143-149ºC

[ Molecular Formula ]:
C₄₆H₆₅Cl₂N₂PRu

[ Molecular Weight ]:
848.971

[ Exact Mass ]:
848.330627

[ PSA ]:
20.07000

[ LogP ]:
13.86190

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H228

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
F

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36/37/39

[ RIDADR ]:
1325

[ WGK Germany ]:
3

[ Packaging Group ]:
Ⅱ

Precursor & DownStream

Precursor

DownStream

Hoveyda-Grubbs II
(E)-But-2-ene-1,4-diyl diacetate
Cinnamyl acetat

Articles

Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts.

Chem. Rev. 110 , 1746, (2010)

Olefin Metathesis and Beyond A list of abbreviations can be found at the end of this article.

Angew. Chem. Int. Ed. Engl. 39 , 3012, (2000)

The advent of well-defined catalysts for olefin metathesis which combine high activity, durability, and excellent tolerance towards polar functional groups has revolutionized the field. The past decad...

Highly Efficient Ring-Opening Metathesis Polymerization (ROMP) Using New Ruthenium Catalysts Containing N-Heterocyclic Carbene Ligands C.B. is grateful to the National Science Foundation for a pre-doctoral fellowship. The authors thank Dr. Matthias Scholl for providing catalysts 4 a and 4 c.

Angew. Chem. Int. Ed. Engl. 39 , 2903, (2000)

Hoveyda-Grubbs Catalyst 2nd Generation
Grubbs Catalyst M104
Tri(i-propoxy)phosphine(3-phenyl-1H-inden-1-ylidene)[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene]ruthenium (II) dichloride
Grubbs Catalyst M207
Benzylidenebis(tricyclohexylphosphine)dichlororuthenium
DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)
2-{[1-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclopropyl]formamido}-4-methylhexanoic acid
2-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylpropanamido]-4-methylhexanoic acid
2-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methoxybutanamido]pent-4-ynoic acid
5-Fluoro-1-benzofuran-3-sulfonyl fluoride
2-(2-Cyclopropylethynyl)-6-[(piperidin-3-yl)methoxy]pyrazine
3-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4,4-dimethylpentanamido]-2-methoxypropanoic acid
rac-(3aR,6aR)-3a-(aminomethyl)-N-(2-methoxyethyl)-octahydrocyclopenta[b]pyrrole-1-carboxamide
2-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4,4-dimethyl-N-(2-methylpropyl)pentanamido]acetic acid
2-{[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4,4-dimethylpentanamido]methyl}pentanoic acid
4-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4,4-dimethylpentanamido]-4-methylpentanoic acid

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