Grubbs Catalyst 2nd Generation

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Names

[ CAS No. ]:
246047-72-3

[ Name ]:
Grubbs Catalyst 2nd Generation

[Synonym ]:
GRUBB'S SECOND GENERATION CATALYST
(1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium
[1,3-Bis-(2,4,6-trimethylpheny
MFCD03453237
Grubb's 2nd generation catalyst
Benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium - tricyclohexylphosphine (1:1)
Phosphine, tricyclohexyl-, compd. with [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)ruthenium (1:1)
Grubbs catalyst,2nd Generation
Grubbs 2

Chemical & Physical Properties

[ Melting Point ]:
143-149ºC

[ Molecular Formula ]:
C46H65Cl2N2PRu

[ Molecular Weight ]:
848.971

[ Exact Mass ]:
848.330627

[ PSA ]:
20.07000

[ LogP ]:
13.86190

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H228

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
F

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36/37/39

[ RIDADR ]:
1325

[ WGK Germany ]:
3

[ Packaging Group ]:
Ⅱ

Precursor & DownStream

Precursor

DownStream

  • Hoveyda-Grubbs II
  • (E)-But-2-ene-1,4-diyl diacetate
  • Cinnamyl acetat

Articles

Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts.

Chem. Rev. 110 , 1746, (2010)

Olefin Metathesis and Beyond A list of abbreviations can be found at the end of this article.

Angew. Chem. Int. Ed. Engl. 39 , 3012, (2000)

The advent of well-defined catalysts for olefin metathesis which combine high activity, durability, and excellent tolerance towards polar functional groups has revolutionized the field. The past decad...

Highly Efficient Ring-Opening Metathesis Polymerization (ROMP) Using New Ruthenium Catalysts Containing N-Heterocyclic Carbene Ligands C.B. is grateful to the National Science Foundation for a pre-doctoral fellowship. The authors thank Dr. Matthias Scholl for providing catalysts 4 a and 4 c.

Angew. Chem. Int. Ed. Engl. 39 , 2903, (2000)


More Articles

Related Compounds

  • Hoveyda-Grubbs Catalyst 2nd Generation
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  • Grubbs Catalyst M207
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  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide