Allyltributyltin

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Names

[ CAS No. ]:
24850-33-7

[ Name ]:
Allyltributyltin

[Synonym ]:
Stannane, tributyl-2-propenyl-
Allyltri-n-butyltin Allyltributyltin Tributyl-2-propenylstannane
EINECS 246-494-3
allyltri-n-butylstannane
Allyltributylstannane
Stannane,tributyl-2-propenyl
ghl.PD_Mitscher_leg0.523
Allyl(tributyl)stannane
Allyltributyltin
tri-n-butyl-2-propenylstannane
MFCD00010346
tri-N-butylallylstannane
Allyltri-n-Butyltin
(prop-1-en-3-yl)(tri-n-butyl)tin
CH2=CHCH2SnBu3
Stannane, tributyl-2-propen-1-yl-

Chemical & Physical Properties

[ Density]:
1.068 g/mL at 25 °C(lit.)

[ Boiling Point ]:
312.3±35.0 °C at 760 mmHg

[ Molecular Formula ]:
C15H32Sn

[ Molecular Weight ]:
331.125

[ Flash Point ]:
146.6±13.0 °C

[ Exact Mass ]:
332.152588

[ LogP ]:
9.10

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.486(lit.)

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H312-H315-H319-H372-H410

[ Precautionary Statements ]:
Missing Phrase - N15.00950417-P260-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R21;R25;R36/38;R48/23/25;R50/53

[ Safety Phrases ]:
S35-S36/37/39-S45-S60-S61

[ RIDADR ]:
UN 2788 6.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2931900090

Synthetic Route

Precursor & DownStream

Precursor

  • allyl bromide
  • Tributyltin oxide
  • Chlorotributyltin
  • Allylmagnesium chloride
  • Allyl(bromo)magnesium
  • 2-propenyllithium
  • Hexabutylditin
  • l'α-chloro α-ethoxymethyltributyletain
  • Lithium
  • ALLYL CHLORIDE

DownStream

  • 3-methyl-1-phenylhex-5-en-1-one
  • 2-[1-(furan-2-yl)but-3-enyl]propanedinitrile
  • 3-prop-2-enyloxolan-2-one
  • N-(2-prop-2-enylphenyl)benzamide
  • Ethyl 2-methyl-4-pentenoate
  • 2-Phenyl-4-penten-2-ol
  • 1-allyl-2-methoxybenzene
  • Estragole
  • Ethyl allylmalonate
  • Diethyl diallylmalonate

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

J. Am. Chem. Soc. 115 , 8467, (1993)

Tetrahedron Lett. 34 , 7827, (1993)

J. Am. Chem. Soc. 35 , 4639, (1994)


More Articles


Related Compounds

  • 2-(methoxycarbonyl)allyltributyltin
  • (4-Bromo-1-naphthyl)trimethylsilane
  • N-[(1,1-Dimethylethoxy)carbonyl]-I(2)-alanine 4-[[[(4-nitrophenoxy)carbonyl]oxy]methyl]phenyl ester
  • 2-(1,3-Thiazol-2-yl)butan-2-amine hydrochloride
  • 3-Amino-1-phenylpropane-1,2-diol
  • 1-Bromo-2-methyl-5-nitro-3-(trifluoromethyl)benzene
  • Methyl 2-(2,4-difluorophenyl)prop-2-enoate
  • N-(1-cyanocyclopentyl)-2-[(2-hydroxy-2-phenylethyl)sulfanyl]acetamide
  • N-(1-cyano-1,2-dimethylpropyl)-2-[(2-hydroxy-2-phenylethyl)sulfanyl]acetamide
  • (1S,2S)-1-amino-1-(4-fluoro-3-methoxyphenyl)propan-2-ol
  • 4-(4-Ethylpiperazin-1-yl)-3,5-difluoroaniline
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