BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)
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Names
[ CAS No. ]:
251567-28-9
[ Name ]:
BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)
[Synonym ]:
[Pd(NCOC2H4CO)(PPh3)2Br]
cis-Pd(PPh3)2(N-Succ)Br
Bromobis(triphenylphosphine)(N-succinimide)palladium(II)
cis-Pd(PPh3)2(N-succinimidate)Br
trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II)
bromobis(triphenylphosphine)(N-succinimide)palladiun(II)
Chemical & Physical Properties
[ Melting Point ]:
223-228ºC (dec.)(lit.)
[ Molecular Formula ]:
C40H34BrNO2P2Pd
[ Molecular Weight ]:
808.97500
[ Exact Mass ]:
807.02800
[ PSA ]:
79.67000
[ LogP ]:
3.46500
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ RIDADR ]:
NONH for all modes of transport
Articles
Org. Lett. 9 , 5397, (2007)
trans-PdBr(N-Succ)(PPh3)2 (1) is a universally effective precatalyst for Suzuki-Miyaura cross-couplings of benzylic halides with aryl- or heteroarylboronic acids. Substituted aryl halides and halogena...