Methyl 2,2,2-trichloroacetimidate

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Names

[ CAS No. ]:
2533-69-9

[ Name ]:
Methyl 2,2,2-trichloroacetimidate

[Synonym ]:
Methyl 2,2,2-trichloroethanimidoate
MFCD00001759
METHYL TRICHLOROACETIMIDATE
Methyl 2,2,2-trichloroacetimidate
trichloroacetic acid methyl imino ester
Ethanimidic acid, 2,2,2-trichloro-, methyl ester
EINECS 219-796-8
methyl 2,2,2,-trichloroacetimidate
trichloromethyl acetimidate
2,2,2-trichloroacetimidic acid methyl ester
Methyl 2,2,2-trichloroethanimidate

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
148.5±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C3H4Cl3NO

[ Molecular Weight ]:
176.429

[ Flash Point ]:
73.9±0.0 °C

[ Exact Mass ]:
174.935852

[ PSA ]:
33.08000

[ LogP ]:
1.60

[ Vapour Pressure ]:
5.3±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.494

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2925290090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Sodium Methylate
  • Trichloroacetonitrile
  • Methanol

DownStream

  • 1H-Benzimidazole, 6-chloro-2-(trichloromethyl)-
  • 2,3-Dimethyl-6-nitro-2H-indazole
  • 2-Oxazolamine,4,5-dihydro-
  • 2,2,2-trichloroethanimidamide
  • methyl formate
  • 2,2,2-Trichloroacetamide
  • 2-methyl-6-nitro-2H-indazole
  • 2-Methyl-5-nitro-2H-indazole
  • TRIS(PHENYL,METHYLPHENYL,ETHYLPHENYLANDNONYLPHENYL)PHOSPHATE
  • 2-METHYL-7-NITRO-2H-INDAZOLE

Customs

[ HS Code ]: 2925290090

[ Summary ]:
2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Efficient synthesis and characterization of novel bibenzimidazole oligomers and polymers as potential conjugated chelating ligands.

J. Org. Chem. 70(23) , 9436-46, (2005)

[Structure: see text]. A simple and mild condensation route for the synthesis of novel bibenzimidazole oligomers and polymers is reported here using methyl 2,2,2-trichloroacetimidate as a key starting...

A new sequence isomer of AB-polybenzimidazole for high-temperature PEM fuel cells. Gulledge AL, et al.

J. Polym. Sci. A Polym. Chem. 50(2) , 306-313, (2012)


More Articles

Related Compounds

  • (1,3-dioxoisoindolin-2-yl)methyl 2,2,2-trichloroacetimidate
  • Methyl 2-(2,2,2-trifluoro-1-{[(4-methylphenyl)sulfonyl]amino}ethy l)pentanoate
  • methyl 2-[2-(2-methoxy-2-oxoethyl)phenyl]acetate
  • methyl 2-(2,2,2-trifluoroethylsulfonyl)acetate
  • Methyl 2-(2,2,2-trifluoro-1-{[(4-methylphenyl)sulfonyl]amino}ethy l)hexanoate
  • methyl 2-[2-(2-hydroxyphenyl)ethyl]benzoate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 1-(1,1,2,2-Tetrafluoroethyl)cyclobutane-1-carboxylic acid
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide