6-Methyl-2-benzothiazolamine

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Names

[ CAS No. ]:
2536-91-6

[ Name ]:
6-Methyl-2-benzothiazolamine

[Synonym ]:
6-Methyl-2-benzothiazolylamine
6-Methyl-1,3-benzothiazol-2(3H)-imine
6-methyl-1,3-benzothiazol-2-amine
6-Methylbenzo[d]thiazol-2-amine
6-Methyl-2-aminobenzothiazole
2-Benzothiazolamine, 6-methyl-
2-Benzothiazolamine,6-methyl
2(3H)-Benzothiazolimine, 6-methyl-
2-amino-6-methyl-benzthiazole
6-Methyl-2-benzothiazolamine
BENZOTHIAZOLE,2-AMINO-6-METHYL
2-Amino-6-methylbenzothiazole
2-amino-6-methyl-benzothiazole
MFCD00005789
2-Methylbenzothiazol-2-amine
EINECS 219-801-3

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
288.6±33.0 °C at 760 mmHg

[ Melting Point ]:
140-142 °C(lit.)

[ Molecular Formula ]:
C8H8N2S

[ Molecular Weight ]:
164.227

[ Flash Point ]:
128.3±25.4 °C

[ Exact Mass ]:
164.040817

[ PSA ]:
67.15000

[ LogP ]:
2.00

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.716

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DL2625000
CHEMICAL NAME :
Benzothiazole, 2-amino-6-methyl-
CAS REGISTRY NUMBER :
2536-91-6
BEILSTEIN REFERENCE NO. :
0122040
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C8-H8-N2-S
MOLECULAR WEIGHT :
164.24
WISWESSER LINE NOTATION :
T56 BN DSJ CZ G1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
84 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 105,486,1952

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
DL2625000

[ HS Code ]:
2934200090

Precursor & DownStream

Precursor

  • 1-(4-Methylphenyl)thiourea
  • Potassium thiocyanate
  • p-Toluidine
  • 4-Methylcyclohexanone
  • N,N,N-Tributyl-1-butanaminium thiocyanate
  • 4-Nitroaniline
  • 4-Methylaniline hydrochloride
  • 6-Methyl-2-mercaptobenzothiazole

DownStream

  • 2-bromo-6-methylbenzo[d]thiazole
  • 2-chloro-6-methylbenzo[d]thiazole
  • 2-chloro-N-(6-methyl-1,3-benzothiazol-2-yl)acetamide
  • Ethyl 2-amino-benzothiazole-6-carboxylate
  • 2-aMinobenzothiazole-6-carboxylic acid
  • N-(6-Methyl-1,3-benzothiazol-2-yl)acetamide
  • 6-Methyl-Benzothiazole
  • 3-(diethylamino)-6-[(6-methyl-1,3-benzothiazol-2-yl)hydrazinylidene]cyclohexa-2,4-dien-1-one
  • 4-Methylmercaptoaniline
  • 2-[(2-amino-5-methylphenyl)disulfanyl]-4-methylaniline

Customs

[ HS Code ]: 2934200090

[ Summary ]:
2934200090. other compounds containing in the structure a benzothiazole ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

New 4-thiazolidinones of nicotinic acid with 2-Amino-6-methylbenzothiazole and their biological activity.

Sci. Pharm. 78(4) , 753-65, (2010)

The title compounds 6aâj, 2-[(6-methyl-1,3-benzothiazol-2-yl)amino]-N-[2-(substituted phenyl/furan-2-yl)-4-oxo-1,3-thiazolidin-3-yl]nicotinamides, were prepared from 2-chloropyridine-3-carboxylic acid...

Centrally acting muscle relaxants in tetanus.

Br. J. Pharmacol. Chemother. 17 , 507-18, (1961)

The anti-tetanus activity of a number of phenothiazine derivatives and other centrally acting muscle relaxants, such as mephenesin, dicyclopropyl ketoxime, 2-amino-6-methylbenzothiazole and meprobamat...


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Related Compounds

  • 6-methyl-2-ethoxycarbonylaminopyridine-N-oxide
  • 6-methyl-2,3,3a,4-tetrahydro-1H-acenaphthylen-5-one
  • 6-Methyl-2-pyridin-2-ylquinoline-4-carboxylic acid
  • 6-Methyl-2-pyridin-4-ylquinoline-4-carboxylic acid
  • 6-METHYL-2-(4-METHYLPHENYL)QUINOLINE-4-CARBOXYLICACID
  • 6-Methyl-2-(3-methylphenyl)quinoline-4-carboxylic acid
  • 4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-5-(octahydro-1H-indol-1-yl)-5-oxopentanoic acid
  • 5-[3-(Trifluoromethoxy)phenyl]-1,2-oxazole-4-carboxylic acid
  • N-[2-(1,3-Dihydro-1,3-dioxo-2H-isoindol-2-yl)-4-methyl-1-oxopentyl]glycine ethyl ester
  • 3-[2-(Dimethylamino)pyridin-3-yl]-2-hydroxy-2-methylpropanoic acid
  • 1-(4-Phenylbut-3-en-1-yl)cyclopropan-1-amine
  • 5-[(4-Methylpiperidin-4-yl)oxy]pyrimidine
  • 3-[(2-Phenylphenyl)methyl]pyrrolidin-3-ol
  • (2R)-2-{[6-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pyridin-2-yl]formamido}-3,3-dimethylbutanoic acid
  • 1-(1-methyl-3-phenyl-1H-pyrazol-5-yl)cyclopropan-1-ol
  • 1-methyl-5-(5-methyl-1,2-oxazol-4-yl)-1H-pyrazole-4-carboxylic acid
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