2-METHOXYFURAN

Names

[ Name ]:
2-METHOXYFURAN

[Synonym ]:
2-Furyl Methyl Ether
Furan,2-methoxy
2-Methoxyfuran
methoxyfuran
2-methoxyfurane
MFCD00003227
2-methoxy-furan
EINECS 246-953-8

Chemical & Physical Properties

[ Density]:
1.065 g/mL at 25 °C(lit.)

[ Boiling Point ]:
110-111°C

[ Molecular Formula ]:
C₅H₆O₂

[ Molecular Weight ]:
98.09990

[ Flash Point ]:
50 °F

[ Exact Mass ]:
98.03680

[ PSA ]:
22.37000

[ LogP ]:
1.28820

[ Vapour Pressure ]:
27.8mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.447(lit.)

[ Storage condition ]:
0-6°C

MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Highlyflammable;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S16-S29-S33

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2932190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-Bromofuran
Sodium Methylate
2,5-Dimethoxy-2,5-dihydrofuran
2-Furancarboxylicacid,5-methoxy-(9CI)
2-Furancarboxylicacid,5-methoxy-,methylester

DownStream

Methyl 2-methoxybenzoate
Methyl 3-methoxybenzoate
4-Methoxy-2-benzofuran-1,3-dione
5-methoxyfuran-2-carbaldehyde
fumaraldehydic acid methyl ester
2-Methoxybenzonitrile
methyl 2,5-dimethoxybenzoate
METHYL 5-HYDROXY-2-METHOXY BENZOATE
4,7-dimethoxy-1,3-benzodioxole
4,5,8-trimethoxy-6,7-methylenedioxynaphthalen-1-ol

Customs

[ HS Code ]: 2932190090

[ Summary ]:
2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Structural studies on cycloadducts of furan, 2-methoxyfuran, and 5-trimethylsilylcyclopentadiene with maleic anhydride and N-methylmaleimide.

J. Org. Chem. 73 , 151-156, (2008)

The early stages of the retro-Diels-Alder reaction are clearly apparent in the structures of the cycloadducts formed between furan or 5-trimethylsilylcyclopentadiene with maleic anhydride and N-methyl...

Asymmetric Friedel-Crafts alkylation of methoxyfuran with nitroalkenes catalyzed by diphenylamine-tethered bis(oxazoline)-Zn(II) complexes.

Org. Lett. 9(23) , 4725-8, (2007)

The first catalytic asymmetric Friedel-Crafts reaction of 2-methoxyfuran with nitroalkenes was developed under the catalysis of diphenylamine-tethered bis(oxazoline)-Zn(OTf)2 complexes. The reaction c...

General Acid Catalysis in the Hydrolysis of a Furan Derivative. KANKAANPERA A and AALTONEN R.

Acta Chem. Scand. 26(6) , 2537- 2540, (1972)

4-bromo-2-methoxyfuran
1-(2-methoxyfuran-3-yl)ethanone
methyl tetrahydro-2-methoxyfuran-2-carboxylate
2-(5-methoxyfuran-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
2-[(5-methoxyfuran-2-yl)methylamino]ethanol
2-[(5-methoxyfuran-2-yl)methylsulfanyl]ethanol
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
methyl 2-(2-methoxy-2-oxoethyl)sulfanyl-3H-benzimidazole-5-carboxylate
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
(4-Methyl-tetrahydro-furan-2-yl)-methanol
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
1-(1-(3-Fluorophenyl)-5-oxopyrrolidin-3-yl)-3-(4-isopropylphenyl)urea
4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
tert-Butyl-DL-alanine