Trichloromethanesulfonyl chloride

Suppliers

Names

[ Name ]:
Trichloromethanesulfonyl chloride

[Synonym ]:
Trichlor-methansulfonylchlorid
Trichloromethane sulfonyl chloride
trichlormethanesulfonyl chloride
Trichloromethylsulfonyl chloride
Methanesulfonyl chloride,trichloro
EINECS 219-830-1
MFCD00007452
TrichloroMethanesulfonyl Chloride

Chemical & Physical Properties

[ Density]:
1.951g/cm3

[ Boiling Point ]:
181.7ºC at 760mmHg

[ Melting Point ]:
137-140 °C(lit.)

[ Molecular Formula ]:
CCl₄O₂S

[ Molecular Weight ]:
217.88700

[ Flash Point ]:
63.7ºC

[ Exact Mass ]:
215.83700

[ PSA ]:
42.52000

[ LogP ]:
2.96350

[ Vapour Pressure ]:
1.14mmHg at 25°C

[ Index of Refraction ]:
1.536

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R34;R36/37

[ Safety Phrases ]:
S26-S27-S28-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2904909090

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

TRICHLOROMETHANESULFONYL CHLORIDE AS A SELECTIVE CHLORINATING AGENT1. Huyser ES.

J. Am. Chem. Soc. 82(19) , 5246-47, (1960)

Homolytic displacement at saturated carbon. Part 9. The reactions of trichloromethanesulfonyl chloride with pent-4-enylcobaloximes and with olefins. A novel route to (trichloroethyl) sulfolanes via an SHi mechanism. Ashcroft MR, et al.

J. Org. Chem. 49(10) , 1751-61, (1984)

Reactions of trichloromethanesulfonyl chloride and carbon tetrachloride with silyl enol ethers catalyzed by a ruthenium (II) phosphine complex. Kamigata N, et al.

J. Organomet. Chem. 552(1) , 9-43, (1998)

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