Mecarbam

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Names

[ CAS No. ]:
2595-54-2

[ Name ]:
Mecarbam

[Synonym ]:
Murphotox
MFCD00129669
Marfotoks
MECARBAM
Murfotox
S-(N-ethoxycarbonyl-N-methylcarbamoylmethyl) O,O-diethyl phosphorodithioate
Pestan
EINECS 219-993-9
Criotox
ethyl 6-ethoxy-2-methyl-3-oxo-7-oxa-5-thia-2-aza-6-phosphanonanoate 6-sulfide
Pennsalt TD-72
AFOS
Caswell No. 340
ethyl [(diethoxyphosphinothioylthio)acetyl](methyl)carbamate
Mercarbam
Mecarbame
ethyl (6Ξ)-6-ethoxy-2-methyl-3-oxo-6-sulfanylidene-7-oxa-5-thia-2-aza-6λ5-phosphanonan-1-oate
ethyl N-(2-diethoxyphosphinothioylsulfanylacetyl)-N-methylcarbamate

Chemical & Physical Properties

[ Density]:
1.265 g/cm3

[ Boiling Point ]:
421.4ºC at 760 mmHg

[ Melting Point ]:
<25℃

[ Molecular Formula ]:
C10H20NO5PS2

[ Molecular Weight ]:
329.37300

[ Flash Point ]:
>100 °C

[ Exact Mass ]:
329.05200

[ PSA ]:
132.27000

[ LogP ]:
3.28260

[ Vapour Pressure ]:
2.62E-07mmHg at 25°C

[ Index of Refraction ]:
1.523

[ Storage condition ]:
APPROX 4°C

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
FB3850000
CHEMICAL NAME :
Carbamic acid, (mercaptoacetyl)methyl-, ethyl ester, S-ester with O,O- diethyl phosphorodithioate
CAS REGISTRY NUMBER :
2595-54-2
LAST UPDATED :
199710
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C10-H20-N-O5-P-S2
MOLECULAR WEIGHT :
329.40
WISWESSER LINE NOTATION :
2OVN1&V1SPS&O2&O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
31 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
BOCKAF Bochu Kagaku. Scientific Pest Control. (Kyoto, Japan) V.1-42, 1937-77. Discontinued. Volume(issue)/page/year: 26,69,1961
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
700 mg/m3/6H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,538,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
380 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
WRPCA2 World Review of Pest Control. (London, UK) V.1-10, 1962-71. Discontinued. Volume(issue)/page/year: 9,119,1970
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
36 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971 Volume(issue)/page/year: -,364,1971
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
106 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,323,1973
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
60 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
BOCKAF Bochu Kagaku. Scientific Pest Control. (Kyoto, Japan) V.1-42, 1937-77. Discontinued. Volume(issue)/page/year: 26,69,1961
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
65 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
BOCKAF Bochu Kagaku. Scientific Pest Control. (Kyoto, Japan) V.1-42, 1937-77. Discontinued. Volume(issue)/page/year: 26,69,1961
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
50 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JEENAI Journal of Economic Entomology. (Entomological Soc. of America, 4603 Calvert Rd., College Park, MD 20740) V.1- 1908- Volume(issue)/page/year: 62,934,1969

Safety Information

[ Symbol ]:

GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H311-H410

[ Precautionary Statements ]:
P273-P280-P301 + P310-P312-P501

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;N: Dangerous for the environment;Xn: Harmful;F: Flammable;

[ Risk Phrases ]:
24/25-50/53-36-20/21/22-11

[ Safety Phrases ]:
36/37-45-60-61-36-26-16

[ RIDADR ]:
3018

[ WGK Germany ]:
3

[ RTECS ]:
FB3850000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
2930909064

Customs

[ HS Code ]: 2930909064

[ Summary ]:
2930909064 s-((n-(2-chlorophenyl)butyramido)methyl) o,o-dimethyl phosphorodithioate

Articles

Experiences with acute organophosphate poisonings in Crete.

Vet. Hum. Toxicol. 38(2) , 101-7, (1996)

Nine human acute poisonings due to intentional ingestion of organophosphorous pesticides are presented. Six of the victims died. Six patients were treated in the Intensive Care Unit (ICU) from 34 h to...

Gas chromatographic determination of mecarbam and its metabolites mecarboxon, diethoate, and diethoxon in cottonseeds.

J. Assoc. Off. Anal. Chem. 70(5) , 870-4, (1987)

A gas chromatographic method is described for determining residues of mecarbam and 3 of its metabolites, mecarboxon, diethoate, and diethoxon, in cottonseeds. For mecarbam analysis, following Soxhlet ...

Mother-fetus postmortem toxicologic analysis in a fatal overdose with mecarbam.

Forensic Sci. Int. 35(4) , 249-52, (1987)

A suicidal poisoning committed by a 19-year-old pregnant woman, who ingested an unknown quantity of an aqueous solution mecarbam (trade name includes 'Murfotox') containing 68 g/l of S-(N-ethoxycarbon...


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