Hydrazine hydrochloride

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Names

[ CAS No. ]:
2644-70-4

[ Name ]:
Hydrazine hydrochloride

[Synonym ]:
MFCD00044368
Hydrazine, hydrochloride
Hydrazine monohydroc
HydrazineHCl
Hydrazine, hydrochloride (1:1)
diazanium, chloride (1:1)
Hydrazinium chloride
Hydrazine hydrochloride (1:1)
hydrazine monochloride
Hydrazine hydrochloride,mono
EINECS 220-154-4
diamide hydrochloride
Hydrazine,chloride
Hydrazine chlorhydrate
HYDRAZINE, MONOHYDROCHLORIDE
HYDRAZINE MONO HCL
hydrazine hydrochloride
Hydrazinium monochloride

Chemical & Physical Properties

[ Boiling Point ]:
240°C

[ Melting Point ]:
89 °C(lit.)

[ Molecular Formula ]:
H5ClN2

[ Molecular Weight ]:
68.506

[ Flash Point ]:
240ºC

[ Exact Mass ]:
68.014130

[ PSA ]:
52.04000

[ LogP ]:
1.02140

[ Water Solubility ]:
370 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MV4625000
CHEMICAL NAME :
Hydrazine, hydrochloride
CAS REGISTRY NUMBER :
2644-70-4
LAST UPDATED :
199710
DATA ITEMS CITED :
13
MOLECULAR FORMULA :
H4-N2.Cl-H
MOLECULAR WEIGHT :
68.52
WISWESSER LINE NOTATION :
ZZ &GH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
128 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
126 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
118 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
126 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
133 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
122 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
53 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
Micronucleus test
TYPE OF TEST :
Specific locus test

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Lung
REFERENCE :
HUGEDQ Human Genetics. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.31- 1976- Volume(issue)/page/year: 54,155,1980 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO HYDRAZINES-air:CA CL 0.03 ppm/120M REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H317-H350-H410

[ Precautionary Statements ]:
P201-P261-P273-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic

[ Risk Phrases ]:
R23/24/25;R43;R45;R50/53

[ Safety Phrases ]:
S53-S45-S60-S61

[ RIDADR ]:
UN 2923 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
MV4625000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
2928000090

Synthetic Route

Precursor & DownStream

Precursor

  • Nitrogen
  • phosphoryl trichloride
  • Sulfuryl chloride
  • Hydrochloric acid
  • Boron, [m-(hydrazine-kN1:kN2)]hexahydrodi-

DownStream

  • 3-Isopropyl-1H-pyrazole
  • 2-Hydrazinobenzothiazole
  • borazine
  • Ethyl 5-hydroxy-1H-pyrazole-3-carboxylate
  • Nitrogen
  • Hydrogen iodide
  • 6-Chloropurine
  • 1,1-Dimethylhydrazine
  • 1,2-Bis-(tert-butyldimethylsilyl)hydrazine

Customs

[ HS Code ]: 2928000090

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

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Int. J. Biol. Macromol. 72 , 11-8, (2014)

Carboxymethylcellulose (CMC) was selected as substrate for amidation based on previous results described for monocarboxy cellulose (MCC) with the aim to prepare highly substituted products. In compari...

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Creation of high-refractive-index amorphous titanium oxide thin films from low-fractal-dimension polymeric precursors synthesized by a sol-gel technique with a hydrazine monohydrochloride catalyst.

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Related Compounds

  • hydrazine hydrochloride
  • p-Tolylhydrazine hydrochloride
  • 3-pentylhydrazine hydrochloride
  • i-propylhydrazine hydrochloride
  • 4-Anisylhydrazine hydrochloride
  • isopentylhydrazine hydrochloride
  • 1-(5-Methoxypyridin-2-yl)cyclopentan-1-amine
  • 1-(4-Methoxypyridin-2-yl)cyclopentan-1-amine
  • 1-(6-Methoxypyridin-2-yl)cyclopentan-1-amine
  • (2R)-2-{5H,6H,7H,8H-[1,2,4]triazolo[4,3-a]pyridin-3-yl}pyrrolidine
  • [1-(2,4-dimethyl-1H-pyrrol-3-yl)cyclopentyl]methanamine
  • 1-(2,4-dimethyl-1H-pyrrol-3-yl)cyclohexan-1-amine
  • (2S)-1-[5-(trifluoromethyl)furan-2-yl]propan-2-amine
  • (2R)-1-[5-(trifluoromethyl)furan-2-yl]propan-2-amine
  • (2R)-1-[3-(trifluoromethyl)-1H-pyrazol-4-yl]propan-2-amine
  • (S)-1-(1-Methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl)ethan-1-amine
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