Methoxycarbonylsulfenyl chloride

Suppliers

Names

[ CAS No. ]:
26555-40-8

[ Name ]:
Methoxycarbonylsulfenyl chloride

[Synonym ]:
metgoxycarbonylsulfenyl chloride
carbomethoxy sulfenyl chloride
MFCD00013648
S-Chloro O-methyl thiocarbonate
Carbonothioic acid,anhydrosulfide with thiohypochlorous acid,methyl ester
Methoxycarbonylsulfenyl chloride
EINECS 247-801-3

Chemical & Physical Properties

[ Density]:
1.399 g/mL at 25 °C(lit.)

[ Boiling Point ]:
133-134 °C(lit.)

[ Molecular Formula ]:
C2H3ClO2S

[ Molecular Weight ]:
126.56200

[ Flash Point ]:
130 °F

[ Exact Mass ]:
125.95400

[ PSA ]:
51.60000

[ LogP ]:
1.63980

[ Index of Refraction ]:
n20/D 1.481(lit.)

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C

[ Risk Phrases ]:
R10:Flammable. R34:Causes burns.

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2920 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2930909090

Synthetic Route

Precursor & DownStream

Precursor

  • Methanol
  • Chloro(chlorosulfanyl)oxomethane

DownStream

  • carbonyl sulfide
  • 3-(2-Pyridyldithio)propanoic Acid
  • methyl (methoxycarbonyltetrasulfanyl)formate
  • methyl (methoxycarbonylpentasulfanyl)formate
  • methyl (methoxycarbonylhexasulfanyl)formate
  • S-(N-methylanilino)sulfanyl N-methyl-N-phenylcarbamothioate

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Anomeric and mesomeric effects in methoxycarbonylsulfenyl chloride, CH(3)OC(O)SCl: an experimental and theoretical study.

Inorg. Chem. 41(5) , 1064-71, (2002)

The molecular structure and conformational properties of methoxycarbonylsulfenyl chloride, CH(3)OC(O)SCl, were determinated in the gas and solid phases by gas electron diffraction, low-temperature X-r...

Nonvolatile S-alk(en)ylthio-L-cysteine derivatives in fresh onion (Allium cepa L. cultivar).

J. Agric. Food Chem. 59(17) , 9457-65, (2011)

The L-cysteine derivatives (R)-2-amino-3-(methyldisulfanyl)propanoic acid (S-methylthio-L-cysteine), (R)-2-amino-3-(propyldisulfanyl)propanoic acid (S-propylthio-L-cysteine), (R)-2-amino-3-(1-propenyl...

Dissociative photoionization of methoxycarbonylsulfenyl chloride, CH3OC(O)SCl, following sulfur 2p, chlorine 2p, and oxygen 1s excitations.

J. Phys. Chem. A 111(33) , 8062-71, (2007)

Total ion yield spectra and photoinduced fragmentations following S 2p, Cl 2p, and O 1s inner shell excitations of methoxycarbonylsulfenyl chloride, CH(3)OC(O)SCl, have been studied in the gaseous pha...


More Articles


Related Compounds

  • Strontium chloride-Sr82
  • Benzoyl chloride, 4-(1-methylpropyl)- (9CI)
  • Benzenebutanoyl chloride, 3-chloro-
  • cyclopentadienylmagnesium chloride
  • Cyclohexanecarbonyl chloride, 2-(acetyloxy)-, trans- (9CI)
  • dodecanoyl chloride,hydrofluoride
  • [4-(Benzyloxy)butyl][(4-chloro-3-methylphenyl)methyl]amine
  • 3-methyl-1-(pyridin-2-yl)-1H-pyrazole-4-carboximidamide
  • 1-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)hex-4-ynoyl]pyrrolidine-3-carboxylic acid
  • 3-(Propane-1-sulfonyl)cyclohexane-1-carboxylic acid
  • Tert-butyl 2-(2-fluoro-1-hydroxyethyl)piperidine-1-carboxylate
  • 2-[2-(Methoxymethyl)oxan-2-yl]propan-2-amine
  • methyl 4-[(1S)-1-hydroxy-3-methoxy-3-oxopropyl]-1-methyl-1H-pyrrole-2-carboxylate
  • 1-[(3,5-Dimethoxyphenyl)methyl]-3-(piperidine-1-carbonyl)piperidine
  • 3-[(1-{Pyrazolo[1,5-a]pyrazin-4-yl}piperidin-3-yl)oxy]pyridine
  • 1,3,3-Trimethyl-1-{1-[(5-methyl-1,2,4-oxadiazol-3-yl)methyl]piperidin-4-yl}urea
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