1,4-Dichloro-2,5-dimethoxybenzene

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Names

[ CAS No. ]:
2675-77-6

[ Name ]:
1,4-Dichloro-2,5-dimethoxybenzene

[Synonym ]:
2,5-dichloro-1,4-dimethoxybenzene
Demasan
1,4-Dichlor-2,5-dimethoxy-benzol
1,4-dichloro-2,5-dimethoxy-benzene
Tersan SP
Demosan
CHLORONEB
1,4-Dichloro-2,5-dimethoxybenzene
Benzene, 1,4-dichloro-2,5-dimethoxy-
Soil fungicide 1823
Terraneb
MFCD00055445
EINECS 220-222-3
Demosan 65W

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
269.3±35.0 °C at 760 mmHg

[ Melting Point ]:
133-135°C

[ Molecular Formula ]:
C8H8Cl2O2

[ Molecular Weight ]:
207.054

[ Flash Point ]:
105.7±26.0 °C

[ Exact Mass ]:
205.990128

[ PSA ]:
18.46000

[ LogP ]:
3.58

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.524

[ Storage condition ]:
0-6°C

[ Stability ]:
Stable.

[ Water Solubility ]:
<0.01 g/100 mL at 23 ºC

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CZ4750000
CHEMICAL NAME :
Benzene, 1,4-dichloro-2,5-dimethoxy-
CAS REGISTRY NUMBER :
2675-77-6
BEILSTEIN REFERENCE NO. :
1952749
LAST UPDATED :
199710
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C8-H8-Cl2-O2
MOLECULAR WEIGHT :
207.06
WISWESSER LINE NOTATION :
1OR BG EG DO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
11 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - wild bird species
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Sex chromosome loss and nondisjunction
TEST SYSTEM :
Mold - Aspergillus nidulans
DOSE/DURATION :
48 umol/L
REFERENCE :
EVHPAZ EHP, Environmental Health Perspectives. (U.S. Government Printing Office, Supt of Documents, Washington, DC 20402) No.1- 1972- Volume(issue)/page/year: 31,81,1979 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

Safety Information

[ Symbol ]:

GHS09

[ Hazard Statements ]:
H411

[ Precautionary Statements ]:
P273

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
N: Dangerous for the environment;

[ Risk Phrases ]:
R51/53

[ Safety Phrases ]:
S61

[ RIDADR ]:
UN3077 9/PG 3

[ RTECS ]:
CZ4750000

[ HS Code ]:
2909309013

Synthetic Route

Precursor & DownStream

Precursor

  • 1,4-Dimethoxybenzene
  • 2,5-Dichloro-1,4-benzoquinone
  • Hydroquinone
  • 2,5-DICHLOROHYDROQUINONE
  • Dimethyl sulfate
  • methyl iodide
  • Phosphorus pentachloride
  • Chlorine

DownStream

  • 2,5-Dichloro-4-methoxyphenol
  • 2,5-Cyclohexadiene-1,4-dione,2,5-dichloro-3,6-diphenyl-
  • 2,5-DICHLOROHYDROQUINONE
  • 2,5-Dichloro-1,4-benzoquinone

Customs

[ HS Code ]: 2909309013

[ Summary ]:
2909309013 1,4-dichloro-2,5-dimethoxybenzene。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:5.5%。general tariff:30.0%

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Related Compounds

  • 1,4-dichloro-2,5-bis(chloromethoxy)benzene
  • 1,4-dichloro-2,5-bis(2-hydroxy-2-naphthamido)benzene
  • 1,4-Dichloro-2,5-difluorobenzene
  • 1,4-dichloro-2,5-bis(dodecylsulfanyl)benzene
  • 1,4-dichloro-2,5-bis-(2,2-dimethoxy-ethylsulfanyl)-benzene
  • 1,4-dichloro-2,5-bis[2-(2,5-dichlorophenyl)ethenyl]benzene
  • 2-{[11-(4-methoxyphenyl)-3,4,6,9,10-pentaazatricyclo[7.3.0.0^{2,6}]dodeca-1(12),2,4,7,10-pentaen-5-yl]sulfanyl}-N-(4-methylphenyl)acetamide
  • 2-{[11-(4-methoxyphenyl)-3,4,6,9,10-pentaazatricyclo[7.3.0.0^{2,6}]dodeca-1(12),2,4,7,10-pentaen-5-yl]sulfanyl}-N-methyl-N-phenylacetamide
  • N-(2-methoxyphenyl)-2-{[11-(4-methoxyphenyl)-3,4,6,9,10-pentaazatricyclo[7.3.0.0^{2,6}]dodeca-1(12),2,4,7,10-pentaen-5-yl]sulfanyl}acetamide
  • N-(4-methoxyphenyl)-2-{[11-(4-methoxyphenyl)-3,4,6,9,10-pentaazatricyclo[7.3.0.0^{2,6}]dodeca-1(12),2,4,7,10-pentaen-5-yl]sulfanyl}acetamide
  • (R)-3-(2H-tetrazol-5-yl)-piperidine
  • N-(2,4-dimethoxyphenyl)-2-{[11-(4-methoxyphenyl)-3,4,6,9,10-pentaazatricyclo[7.3.0.0^{2,6}]dodeca-1(12),2,4,7,10-pentaen-5-yl]sulfanyl}acetamide
  • N-(2,5-dimethoxyphenyl)-2-{[11-(4-methoxyphenyl)-3,4,6,9,10-pentaazatricyclo[7.3.0.0^{2,6}]dodeca-1(12),2,4,7,10-pentaen-5-yl]sulfanyl}acetamide
  • (1S,3S,5R,6S)-5-Hydroxy-3-methyl-7-oxabicyclo[4.1.0]heptan-2-one
  • 2-{[11-(4-methoxyphenyl)-3,4,6,9,10-pentaazatricyclo[7.3.0.0^{2,6}]dodeca-1(12),2,4,7,10-pentaen-5-yl]sulfanyl}-N-[(4-methoxyphenyl)methyl]acetamide
  • Ethyl 4-[3-(11-phenyl-3,4,6,9,10-pentazatricyclo[7.3.0.02,6]dodeca-4,7-dien-5-yl)propanoyl]piperazine-1-carboxylate
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