1-bromo-5-hexene

Names

[ Name ]:
1-bromo-5-hexene

[Synonym ]:
5-Hexenyl Bromide
1-Hexene, 6-bromo-
6-Bromo-1-hexene
1-bromo-5-hexene
6-bromo-hex-1-ene
6-Bromohex-1-Ene
6-bromo-hexene
MFCD00000269
bromo hexene
1-Hexene,6-bromo
EINECS 220-267-9

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
153.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₆H₁₁Br

[ Molecular Weight ]:
163.055

[ Flash Point ]:
52.2±0.0 °C

[ Exact Mass ]:
162.004410

[ LogP ]:
3.34

[ Vapour Pressure ]:
4.4±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.461

[ Storage condition ]:
Refrigerator

[ Stability ]:
Stable. Incompatible with strong oxidizing agents, strong bases. Flammable.

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H315-H319-H335-H360D

[ Precautionary Statements ]:
P201-P261-P305 + P351 + P338-P308 + P313

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39-S16

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2903399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1,6-Dibromohexane
1-Hexen-6-ol
O-hex-5-enyl dimethylcarbamothioate
1,3-Dibromopropane
Allyl(bromo)magnesium
hex-5-en-1-ol,methanesulfonic acid
Hexamethylphosphorous triamide
1,2,6-tribromohexane
UNII:9BYT763GMT
UNII:JR71SUM5E9

DownStream

N-METHYLHEX-5-EN-1-AMINE 4-METHYLBENZENESULFONATE
(Bromomethyl)cyclopentane
6-bromohexanol
tetradeca-1,13-diene-7,8-dione
(4-hex-5-enoxyphenyl)methanol
6-Heptenenitrile
5-Hexenyl Acetate
Carbamic acid, 5-hexenyl-, 1,1-dimethylethyl ester (9CI)
1-decene
1-hexene

Customs

[ HS Code ]: 2903399090

[ Summary ]:
2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Hierarchical superstructures from a star-shaped molecule consisting of a cyclic oligosiloxane with cyanobiphenyl moieties.

Soft Matter 11(1) , 58-68, (2014)

Unconventional star-shaped liquid crystals (abbreviated as SiLCs) were successfully synthesized by chemically connecting four cyanobiphenyl anisotropic mesogens to the periphery of a super-hydrophobic...

Microbial production of aliphatic (S)-epoxyalkanes by using Rhodococcus sp. strain ST-10 styrene monooxygenase expressed in organic-solvent-tolerant Kocuria rhizophila DC2201.

Appl. Environ. Microbiol. 81(6) , 1919-25, (2015)

We describe the development of biocatalysis for producing optically pure straight-chain (S)-epoxyalkanes using styrene monooxygenase of Rhodococcus sp. strain ST-10 (RhSMO). RhSMO was expressed in the...

Synlett , 1616, (2007)