4-Bromo-3-methyl-anisole

Suppliers

Names

[ Name ]:
4-Bromo-3-methyl-anisole

[Synonym ]:
1-Bromo-4-methoxy-2-methylbenzene
2-Bromo-5-methoxytoluene (BMA)
Benzene,1-bromo-4-methoxy-2-methyl
2-BroMo-5-Methoxytoluene
4-Bromo-3-methylphenyl methyl ether
4-Bromo-3-methyl-anisole
1-brom-4-methoxy-2-methylbenzol
Benzene, 1-bromo-4-methoxy-2-methyl-
1-bromo-4-methoxy-2-methyl-benzene
2-methyl-4-methoxybromobenzene
MFCD00060687
4-Bromo-3-methylanisole
4-methoxy-2-methylphenyl bromide
4-bromo-1-methoxy-3-methylbenzene

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
235.3±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C₈H₉BrO

[ Molecular Weight ]:
201.061

[ Flash Point ]:
105.3±7.8 °C

[ Exact Mass ]:
199.983673

[ PSA ]:
9.23000

[ LogP ]:
3.63

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.535

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Efficient aqueous-phase Heck and Suzuki couplings of aryl bromides using tri(4,6-dimethyl-3- sulfonatophenyl)phosphine trisodium salt (TXPTS).

Org. Lett. 6 , 225-228, (2004)

[reaction: see text] Sterically demanding, sulfonated arylphosphines TXPTS and TMAPTS have been applied to the aqueous-phase Heck and Suzuki coupling of aryl bromides. TXPTS provides good yields of He...

Discovery of orally active nonpeptide vitronectin receptor antagonists based on a 2-benzazepine Gly-Asp mimetic.

J. Med. Chem. 43.1 , 22-26, (2000)

A concise synthesis of the naphthoic acid component of neocarzinostatin chromophore featuring a new photocyclization reaction. Myers et al.

Tetrahedron Lett. 37.5 , 587-590, (1996)

4-Bromo-3-methyl-1H-pyrazolo[3,4-b]pyridine
(4-Bromo-3-methyl-1H-pyrazol-5-yl)methanol
4-bromo-3-methyl-N,N-dipentylaniline
4-BROMO-3-METHYL-PYRIDINE-2-CARBONITRILE
4-BROMO-3-METHYL-ISOQUINOLINE
4-Bromo-3-methyl-1H-pyrrolo[2,3-b]pyridine
2-(3-(3-(3-chlorophenyl)-1,2,4-oxadiazol-5-yl)-4,6-dimethyl-2-oxopyridin-1(2H)-yl)-N-(2-methoxy-5-methylphenyl)acetamide
N-benzyl-2-(3-(3-(3-chlorophenyl)-1,2,4-oxadiazol-5-yl)-4,6-dimethyl-2-oxopyridin-1(2H)-yl)acetamide
N-[(2H-1,3-benzodioxol-5-yl)methyl]-2-{3-[3-(3-chlorophenyl)-1,2,4-oxadiazol-5-yl]-4,6-dimethyl-2-oxo-1,2-dihydropyridin-1-yl}acetamide
2-(3-(3-(3-chlorophenyl)-1,2,4-oxadiazol-5-yl)-4,6-dimethyl-2-oxopyridin-1(2H)-yl)-N-(3-methoxybenzyl)acetamide
2-(3-(3-(3-chlorophenyl)-1,2,4-oxadiazol-5-yl)-4,6-dimethyl-2-oxopyridin-1(2H)-yl)-N-(2-methoxybenzyl)acetamide
2-(3-(3-(3-chlorophenyl)-1,2,4-oxadiazol-5-yl)-4,6-dimethyl-2-oxopyridin-1(2H)-yl)-N-phenethylacetamide
2-(3-(3-(4-bromophenyl)-1,2,4-oxadiazol-5-yl)-4,6-dimethyl-2-oxopyridin-1(2H)-yl)-N-(2-fluorophenyl)acetamide
2-(2,5-Dimethylbenzyl)-6-{2-[4-(4-fluorophenyl)piperazin-1-yl]-2-oxoethyl}-1,2,6-thiadiazinane 1,1-dioxide
3-{3-[4-(2-fluorophenyl)piperazin-1-yl]-3-oxopropyl}-2H-1,2,4-benzothiadiazine 1,1-dioxide
2-(5-amino-4-(3-(4-chlorophenyl)-1,2,4-oxadiazol-5-yl)-3-(methylthio)-1H-pyrazol-1-yl)-N-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)acetamide

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