(3-bromophenyl)hydrazine hydrochloride

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Names

[ Name ]:
(3-bromophenyl)hydrazine hydrochloride

[Synonym ]:
MFCD00012933
(3-Bromophenyl)hydrazine HCl
3-Bromophenylhydrazinehydrochloride
EINECS 248-362-0
Hydrazine, (3-bromophenyl)-, hydrochloride (1:1)
(3-bromophenyl)hydrazine hydrochloride
3-Bromophenylhydrazine hydrochloride
(3-Bromophenyl)hydrazine hydrochloride (1:1)
3-bromophenylhydrazine hydrochloric acid salt

Chemical & Physical Properties

[ Boiling Point ]:
286ºC at 760 mmHg

[ Melting Point ]:
227-231 °C (dec.)(lit.)

[ Molecular Formula ]:
C₆H₈BrClN₂

[ Molecular Weight ]:
223.498

[ Flash Point ]:
126.7ºC

[ Exact Mass ]:
221.955933

[ PSA ]:
38.05000

[ LogP ]:
3.31000

[ Vapour Pressure ]:
0.00272mmHg at 25°C

[ Index of Refraction ]:
1.68

[ Storage condition ]:
Room temperature.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MV0815000

CHEMICAL NAME :: Hydrazine, (m-bromophenyl)-, monohydrochloride

CAS REGISTRY NUMBER :: 27246-81-7

LAST UPDATED :: 198803

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C6-H7-Br-N2.Cl-H

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2400 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: QJDRAZ Quarterly Journal of Crude Drug Research. (Lisse, Netherlands) V.1-19, 1961-81. For publisher information, see IJCREE. Volume(issue)/page/year: 9,1455,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 200 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: QJDRAZ Quarterly Journal of Crude Drug Research. (Lisse, Netherlands) V.1-19, 1961-81. For publisher information, see IJCREE. Volume(issue)/page/year: 9,1455,1969

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37/39-S45-S37/39

[ RIDADR ]:
UN 1759 8/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
MV0815000

[ Packaging Group ]:
I; II; III

[ Hazard Class ]:
8.0

[ HS Code ]:
2928000090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2928000090

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Synthesis and COX inhibitory activities of rutaecarpine derivatives.

Bull. Korean Chem. Soc. 26(12) , 1975, (2005)

[(3-bromophenyl)methyl]hydrazine hydrochloride
(4-Bromophenyl)hydrazine hydrochloride
Cyclopropanamine, 1-(3-bromophenyl)-, hydrochloride (1:1)
ethyl 2-(3-bromophenyl)hydrazine-1-carboxylate
1,2-Bis(3-bromophenyl)hydrazine
3-Bromo-phenylhydrazine
3-(2-Fluoro-4-methoxyphenyl)bicyclo[1.1.1]pentan-1-amine
3-(4-Chloro-2-methylphenyl)bicyclo[1.1.1]pentan-1-amine
3-(3-Chloro-2-methylphenyl)bicyclo[1.1.1]pentan-1-amine
3-(3-Chloro-4-fluorophenyl)bicyclo[1.1.1]pentan-1-amine
3-(4-Chloro-3-methoxyphenyl)bicyclo[1.1.1]pentan-1-amine
3-(2,3-Dichlorophenyl)bicyclo[1.1.1]pentan-1-amine
3-(3,5-Dichlorophenyl)bicyclo[1.1.1]pentan-1-amine
[3-(2-Methylpropyl)-1-bicyclo[1.1.1]pentanyl]hydrazine
[3-(2-Methoxyethyl)-1-bicyclo[1.1.1]pentanyl]hydrazine
[3-(2-Ethoxyethyl)-1-bicyclo[1.1.1]pentanyl]hydrazine

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