1,10-Phenanthroline-5,6-dione

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Names

[ CAS No. ]:
27318-90-7

[ Name ]:
1,10-Phenanthroline-5,6-dione

[Synonym ]:
9,10-phenanthrenequinone
MFCD00014473
1,10-Phenanthroline-5,6-dione
phen-5,6-dione
dipyridobenzoquinone
[1,10]Phenanthroline-5,6-dione
Stahl phd oxidant phd
1 10-Phenanthroline-5 6-Dione

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
456.1±20.0 °C at 760 mmHg

[ Melting Point ]:
260ºC (dec.)

[ Molecular Formula ]:
C12H6N2O2

[ Molecular Weight ]:
210.188

[ Flash Point ]:
229.1±28.2 °C

[ Exact Mass ]:
210.042923

[ PSA ]:
59.92000

[ LogP ]:
0.15

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.678

[ Water Solubility ]:
Insoluble in water.

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933990090

Synthetic Route

Precursor & DownStream

Precursor

  • 1,10-Phenanthroline
  • 1,10-phenanthroline[5,6-d]-1,3-dioxole
  • o-Phenanthroline monohydrate
  • 5-Nitro-1,10-phenanthroline
  • 5,6-Epoxy-1,10-phenanthroline
  • 5-CHLORO-1,10-PHENANTHROLINE
  • 6-Chloro-8-quinolinamine

DownStream

  • 5H-Cyclopenta[2,1-b:3,4-b']dipyridin-5-one
  • dipyridophenazine
  • 3-methylpyrazino[2,3-f][1,10]phenanthroline
  • dipyrido[3,2-f:2′,3′-h]quinoxaline
  • pyrazino[2,3-f][1,10]phenanthroline-2,3-dicarbonitrile
  • 6-(1,3-dihydrophenanthro[9,10-d]imidazol-2-ylidene)cyclohexa-2,4-dien-1-one
  • 5,6-Diamino-1,10-phenanthroline
  • 2,2′-Bipyridine-3,3′−dicarboxylic acid
  • pyrazino[2,3-f][1,10]phenanthroline-2,3-dicarboxylic acid
  • methyl pyrazino[2,3-f][1,10]phenanthroline-3-carboxylate

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Photoinduced intercalation and coordination of a dirhodium complex to DNA: dual DNA binding.

ChemMedChem 9(6) , 1260-5, (2014)

Two new complexes, cis-H,H-[Rh2 (OCCH3 NH)2 (LL)(CH3 CN)2 ](2+) , where LL=bpy (2, bpy=2,2'-bipyridine) and dppz (3, dppz=dipyrido[3,2-a:2',3'-c]phenazine), were prepared from the reaction of cis-H,H-...

Luminescent pH sensor of a novel imidazole-containing hexanuclear Ru(II) polypyridyl complex.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 114 , 159-63, (2013)

Hexapodal ligand H6L containing imidazole rings has been prepared by the reaction of 1,10-phenanthroline-5,6-dione with 1,2,3,4,5,6-hexakis[(3-formylphenoxy)methyl]benzene. The Ru(II) polypyridyl comp...

Synthesis and physicochemical properties of novel lophine derivatives as chemiluminescent in vitro activators for detection of free radicals.

Eur. Biophys. J. 44 , 623-34, (2015)

The overproduction of free radicals and reactive oxygen species (ROS) has been proved as a basic damage mechanism and cause for oxidative stress. Their measurement is often hindered by the low signal....


More Articles


Related Compounds

  • 3-bromo-1,10-phenanthroline-5,6-dione
  • 3-Bromo-1,10-phenanthroline-5,6-dione
  • 2,9-dibutyl-1,10-phenanthroline-5,6-dione
  • 1,10-Phenanthroline-5,6-dione,3,8-dibromo
  • 2,9-dibromo-1,10-phenanthroline-5,6-dione
  • 3,8-dibutyl-1,10-phenanthroline-5,6-dione
  • (S)-2-Amino-3-(4-((6-nitrobenzo[d][1,3]dioxol-5-yl)methoxy)phenyl)propanoic acid
  • (1R,3S,Z)-5-(2-((1R,3AS,7aR,E)-1-((S)-1-hydroxypropan-2-yl)-7a-methyloctahydro-4H-inden-4-ylidene)ethylidene)-4-methylenecyclohexane-1,3-diyl dibenzoate
  • tert-Butyl (9-hydroxy-5-oxaspiro[3.5]nonan-2-yl)carbamate
  • tert-Butyl 6-formyl-4-azaspiro[2.5]octane-4-carboxylate
  • N-Trityl-5'H,7'H-spiro[cyclobutane-1,6'-pyrazolo[5,1-b][1,3]oxazine]-3'-sulfonimidamide
  • Bis(2-(5-chloro-2-(2,4-dichlorobenzyl)phenoxy)-2-oxoethyl) 2,2'-oxydiacetate
  • 1,1-Dimethylethyl N-[1-[2-(2-formyl-4-thiazolyl)ethynyl]cyclopropyl]carbamate
  • (R)-N-((S)-1-(3-(1,1-Difluoro-2-hydroxyethyl)phenyl)ethyl)-2-methylpropane-2-sulfinamide
  • (4Z,8E)-20,20b-Dihydroxy-5',6,6',8,19-pentamethyl-3',4',5',6,6',7,10,11,14,15,17a,20,20a,20b-tetradecahydro-2H,17H-spiro[11,15-methanofuro[4,3,2-pq][2,6]benzodioxacyclooctadecine-13,2'-pyran]-17-one
  • (2S)-N-[(2S,5S,8S,11R,12R,15S,18S,21R)-5-benzyl-8-[(2S)-butan-2-yl]-21-hydroxy-2-[(1R)-1-hydroxyethyl]-15-[(4-hydroxyphenyl)methyl]-4,11-dimethyl-3,6,9,13,16,22-hexaoxo-10-oxa-1,4,7,14,17-pentazabicyclo[16.3.1]docosan-12-yl]-2-[[(2R)-2-hydroxy-3-(4-hydroxyphenyl)propanoyl]amino]pentanediamide
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