2,4-Dimethoxyaniline

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Names

[ CAS No. ]:
2735-04-8

[ Name ]:
2,4-Dimethoxyaniline

[Synonym ]:
2,4-dimethoxylaniline
4-AMINORESORCINOL
2,4,7-TRINITRO-9H-FLUOREN-9-ONE OXIME
1-amino-2,4-dimethoxy-benzene
Benzenamine, 2,4-dimethoxy-
2,4-dimethoxyphenylamine
2,4-dimethoxybenzenamine
EINECS 220-355-7
MFCD00008371
2,4-dimethoxy-aniline
2,4-Dimethoxyaniline
2,4-dimethoxy-anilin
Aniline,2,4-dimethoxy
2,4-dimethoxy-benzenamin
2,4-dimetoxybenzenamine
4-DiMethoxyaniline
2,4-DIMETHOXY BENZAMINE

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
267.1±20.0 °C at 760 mmHg

[ Melting Point ]:
33-36 °C(lit.)

[ Molecular Formula ]:
C8H11NO2

[ Molecular Weight ]:
153.178

[ Flash Point ]:
124.8±29.0 °C

[ Exact Mass ]:
153.078979

[ PSA ]:
44.48000

[ LogP ]:
0.78

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.540

[ Storage condition ]:
Refrigerator

[ Stability ]:
Stability Stable, but sensitive to prolonged exposure to light. Incompatible with acids.

[ Water Solubility ]:
7 g/L (20 ºC)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BX4200000
CHEMICAL NAME :
Aniline, 2,4-dimethoxy-
CAS REGISTRY NUMBER :
2735-04-8
BEILSTEIN REFERENCE NO. :
0638704
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C8-H11-N-O2
MOLECULAR WEIGHT :
153.20
WISWESSER LINE NOTATION :
1OR BZ EO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
464 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Morphological transformation
TEST SYSTEM :
Rodent - rat Embryo
DOSE/DURATION :
55 ug/plate
REFERENCE :
JJATDK JAT, Journal of Applied Toxicology. (John Wiley & Sons Ltd., Baffins Lane, Chichester, W. Sussex PO19 1UD, UK) V.1- 1981- Volume(issue)/page/year: 1,190,1981

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S36-S36/37/39-S22

[ RIDADR ]:
2811

[ WGK Germany ]:
3

[ RTECS ]:
BX4200000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
2922299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1,3-Dimethoxy-4-bromobenzene
  • benzyl 2,4-dimethoxyphenylcarbamate
  • bis(2,4-dimethoxyphenyl)diazene
  • 1,3-dimethyl-2-(2,4-dimethoxyphenylimino)imidazolidine
  • 1-(2,4-dimethoxyphenyl)-1,2-hydrazinedicarboxylic acid bis(2,2,2-trichloroethyl) ester
  • 2,4-Dimethoxybenzonitrile
  • 1,3-Dimethoxybenzene
  • 1-(3'-Chlorophenyl)-3-methyl-5-pyrazolone
  • 2,4-Dimethoxyiodobenzene

DownStream

  • 6,8-dimethoxy-4-oxo-1H-quinoline-3-carboxylic acid
  • 2,4-Dimethoxy-1-nitrobenzene
  • 1-(2,4-dimethoxyphenyl)-2-thiourea
  • 6,8-DIMETHOXY-4-METHYLQUINOLINE
  • 2,4-DIMETHOXYPHENYLISOCYANIDE
  • 1-(4-chlorophenyl)-N-(4-methoxyphenyl)methanimine
  • Benzylideneaniline
  • N-(2,4-dimethoxyphenyl)-3-hydroxynaphthalene-2-carboxamide

Customs

[ HS Code ]: 2922299090

[ Summary ]:
2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Related Compounds

  • 2,4-dimethoxyaniline HCl
  • N-ethyl-2,4-dimethoxyaniline
  • 5-Bromo-2,4-dimethoxyaniline
  • 5-fluoro-2,4-dimethoxyaniline
  • N-phenyl-2,4-dimethoxyaniline
  • 3-Fluoro-2,4-dimethoxyaniline
  • 5-[[1-[[1-[4-[[[4-[[2-[1-Acetyloxy-4-methyl-3-[methyl-[3-methyl-2-[(1-methylpiperidine-2-carbonyl)amino]pentanoyl]amino]pentyl]-1,3-thiazole-4-carbonyl]amino]-2-methyl-5-phenylpentanoyl]amino]oxymethyl]anilino]-6-(carbamoylamino)-1-oxohexan-2-yl]amino]-3-methyl-1-oxobutan-2-yl]amino]-5-oxopentanoic acid
  • 4-[[2-[1-Acetyloxy-3-[[2-[(1,2-dimethylpyrrolidine-2-carbonyl)amino]-3-methylpentanoyl]-methylamino]-4-methylpentyl]-1,3-thiazole-4-carbonyl]amino]-5-[4-[[4-[[5-(carbamoylamino)-2-[[2-[6-(2,5-dioxopyrrol-1-yl)hexanoylamino]-3-methylbutanoyl]amino]pentanoyl]amino]phenyl]methoxycarbonylamino]phenyl]-2-methylpentanoic acid
  • CID 139291196
  • 5,12,15-Trimethyl-11-(6-methylocta-1,3,5-trienyl)-10,21,22-trioxatricyclo[15.3.1.13,7]docos-13-en-9-one
  • (3-Hydroxyphenyl) pent-2-en-3-yl (3-phosphorosooxyphenyl) phosphate
  • 4-O-[2-(1-cyanopent-2-ynylidene)-4-[4-[4-(6-prop-2-enoyloxyhexoxy)phenoxy]carbonylcyclohexanecarbonyl]oxy-1,3-benzodithiol-7-yl] 1-O-[4-[6-(1-hydroxyprop-2-enoxy)hexoxy]phenyl] cyclohexane-1,4-dicarboxylate
  • methyl N-[2-[2-[5-[6-[1-(2-amino-3-methylbutanoyl)-3,3a,4,5,6,6a-hexahydro-2H-cyclopenta[b]pyrrol-2-yl]-21-oxa-5,7-diazapentacyclo[11.8.0.03,11.04,8.014,19]henicosa-1(13),2,4(8),5,9,11,14(19),15,17-nonaen-17-yl]-1H-imidazol-2-yl]-5-methylpyrrolidin-1-yl]-1-(2,6-dimethyloxan-4-yl)-2-oxoethyl]carbamate
  • [2-[17-[3,7-Dimethyl-9-(2,6,6-trimethylcyclohexen-1-yl)nona-2,4,6,8-tetraenoyl]oxy-9-fluoro-11-hydroxy-10,13,16-trimethyl-3-oxo-6,7,8,11,12,14,15,16-octahydrocyclopenta[a]phenanthren-17-yl]-2-oxoethyl] 3,7-dimethyl-9-(2,6,6-trimethylcyclohexen-1-yl)nona-2,4,6,8-tetraenoate
  • 1-[3-[[3-(3,5-Difluorophenyl)-2-[(4-methylphenyl)carbamoylamino]propanoyl]amino]-4,9,13,17-tetramethyl-2,6,12,15,18-pentaoxo-5-oxa-1,11,14,17-tetrazatricyclo[17.3.0.07,11]docosan-16-yl]ethyl dihydrogen phosphate
  • [9-[[3-(3,5-Difluorophenyl)-2-[[3-(trifluoromethoxy)phenyl]carbamoylamino]propanoyl]amino]-10,15,19-trimethyl-2,8,12,18,21-pentaoxo-11-oxa-1,7,17,20-tetrazatetracyclo[20.4.0.03,7.013,17]hexacosan-5-yl] dihydrogen phosphate
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