Dibenzoyl-L-tartaric acid

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Names

[ CAS No. ]:
2743-38-6

[ Name ]:
Dibenzoyl-L-tartaric acid

[Synonym ]:
(2R,3R)-2,3-Bis[(phenylcarbonyl)oxy]butanedioic acid
(-)-Dibenzoyl-L-tartaric Acid
DIBENZOYL-L-TARARIC ACID
DIBENZOYL-L-TARTARIC ACID
(2R,3R)-2,3-bis(benzoyloxy)butanedioic acid
BENZOYL-L-TARTARICACID
(2R,3R)-2,3-Bis(benzoyloxy)succinic acid hydrate
(2R,3R)-2,3-Bis(benzoyloxy)succinic acid hydrate (1:1)
EINECS 220-374-0
Dibenzoyl-L-tartaric
(2R,3R)-2,3-Bis[(phenylcarbonyl)oxy]butanedioic acid hydrate
Butanedioic acid, 2,3-bis(benzoyloxy)-, (2R,3R)-, hydrate (1:1)
DIBENZOYL-L-TARTARIC,I
Dibenzoyl-L-tartric Acid
MFCD00003074
ibenzoyl-L-tartaricacid
(2R,3R)-2,3-Bis(benzoyloxy)succinic acid
Butanedioic acid, 2,3-bis(benzoyloxy)-, (2R,3R)-

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
606.6±55.0 °C at 760 mmHg

[ Melting Point ]:
151-154ºC

[ Molecular Formula ]:
C18H14O8

[ Molecular Weight ]:
358.299

[ Flash Point ]:
221.8±25.0 °C

[ Exact Mass ]:
358.068878

[ PSA ]:
127.20000

[ LogP ]:
5.82

[ Vapour Pressure ]:
0.0±1.8 mmHg at 25°C

[ Index of Refraction ]:
1.609

[ Storage condition ]:
Refrigerator

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WW8070000
CHEMICAL NAME :
Tartaric acid, dibenzoate
CAS REGISTRY NUMBER :
2743-38-6
BEILSTEIN REFERENCE NO. :
0709854
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C18-H14-O8
MOLECULAR WEIGHT :
358.32

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 20,573,1982
TYPE OF TEST :
Rinsed with water
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 20,573,1982

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
WW8070000

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • l-threo-methylphenidate/dibenzoyl L-tartaric acid
  • Dibenzoyl-L-tartaric acid
  • Tartaric acid
  • Benzoyl chloride

DownStream

  • (+)-Dibenzoyl-D-tartaric acid
  • Dibenzoyl-L-tartaric acid
  • (+)-Dibenzoyl-L-tartaric anhydride
  • (+)-Nicotine
  • (R)-3-(dimethylamino)-1-(3-methoxyphenyl)-2-methylpropan-1-one
  • (S)-3-(Dimethylamino)-1-(3-methoxyphenyl)-2-methylpropan-1-one (2R,3R)-2,3-bis(benzoyloxy)succinate

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Enantioselective nanofiber-spinning of chiral calixarene receptor with guest.

Chem. Commun. (Camb.) (32) , 3398-400, (2007)

Chiral para-tert-butylcalix[4]arene bearing (S)-alpha-methylbenzylamine groups at lower rim only self-assembles with one of two enantiomers of 2,3-dibenzoyltartaric acid into coiled nanofibers and the...

Exceptional chiral recognition of racemic carboxylic acids by calix[4]arenes bearing optically pure alpha,beta-amino alcohol groups.

Org. Lett. 6(8) , 1189-92, (2004)

Calixarenes bearing optically pure alpha,beta-amino alcohol groups at their lower rim exhibit exceptional and efficient chiral recognition ability in discrimination of racemic mandelic acid, 2,3-diben...

Delta-opioid agonists: differential efficacy and potency of SNC80, its 3-OH (SNC86) and 3-desoxy (SNC162) derivatives in Sprague-Dawley rats.

J. Pharmacol. Exp. Ther. 309(1) , 173-81, (2004)

The diarylpiperazine delta-opioid agonist SNC80 [(+)-4-[(alphaR)-alpha-[(2S,5R)-2,5-dimethyl-4-(2-propenyl)-1-piperazinyl]-(3-methoxyphenyl)methyl]-N,N-diethylbenzamide] produces convulsions, antidepr...


More Articles

Related Compounds

  • dibenzoyl-L-tartaric acid
  • (-)-DIBENZOYL-L-TARTARIC ACID H2O
  • (-)-2,3-dibenzoyl-L-tartaric acid
  • dibenzoyl-l-tartaric acid monodimethylamide
  • .dibenzoyl-L-tartaric acid monomethyl ester
  • (-)-O,O'-DIBENZOYL-L-TARTARIC ACID MONO(DIMETHYLAMIDE)
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 1-Amino-1-(4-fluoro-2-methylphenyl)acetone
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide