(S)-(-)-2-(FLUORODIPHENYLMETHYL)PYRROLI&

Suppliers

Names

[ Name ]:
(S)-(-)-2-(FLUORODIPHENYLMETHYL)PYRROLI&

[Synonym ]:
I11-1035
(S)-(-)-2-(FLUORODIPHENYLMETHYL)PYRROLI&Pyrrolidine,2-(fluorodiphenylmethyl)-,(2S)
(S)-2-[(fluoro)(diphenyl)methyl]pyrrolidine
MFCD03093547

Chemical & Physical Properties

[ Molecular Formula ]:
C₁₇H₁₈FN

[ Molecular Weight ]:
255.33000

[ Exact Mass ]:
255.14200

[ PSA ]:
12.03000

[ LogP ]:
3.98050

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1,1-diphenyl-5,6,7,7a-tetrahydropyrrolo[1,2-c][1,3]oxazol-3-one
(R)-(+)-2-(Diphenylhydroxymethyl)pyrrolidine
(S)-1-ethyl 2-methyl pyrrolidine-1,2-dicarboxylate

DownStream

Articles

Fluorinated organocatalysts for the enantioselective epoxidation of enals: molecular preorganisation by the fluorine-iminium ion gauche effect.

Chemistry 36th ed., 18 , 11334-11342, (2012)

The fluorine-iminium ion gauche effect is triggered upon union of a secondary β-fluoroamine and an α,β-unsaturated aldehyde, providing a useful strategy for controlling the molecular topology of inter...

Sparr, C.; et al.

Angew. Chem. Int. Ed. Engl. 121 , 3065-3068, (2009)

Zimmer, L. E.; et al.

Angew. Chem. Int. Ed. Engl. 123 , 12062-12074, (2011)

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