Tilorone dihydrochloride

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Names

[ CAS No. ]:
27591-69-1

[ Name ]:
Tilorone dihydrochloride

[Synonym ]:
9H-Fluoren-9-one, 2,7-bis[2-(diethylamino)ethoxy]-, hydrochloride (1:2)
2,7-Bis-deae-fluorenone
2,7-Bis(2-(diethylamino)ethoxy)fluoren-9-one dihydrochloride
2,7-Bis(2-diethylaminoethoxy)fluoren-9-one dihydrochloride
bis-deae-fluorenonehydrochloride
TILORONE HYDROCHLORIDE
TILORONE 2HCL
2,7-Bis[2-(diethylamino)ethoxy]-9-fluorenone dihydrochloride
MFCD00134071
9H-Fluoren-9-one, 2,7-bis[2- (diethylamino)ethoxy]-, dihydrochloride
Tilorone DiHCl
Deae-f
2,7-Bis[2-(diethylamino)ethoxy]-9H-fluoren-9-one dihydrochloride
UNII-BJ507J4LKY
Tilorone (dihydrochloride)

Chemical & Physical Properties

[ Density]:
1.102g/cm3

[ Boiling Point ]:
552.3ºC at 760 mmHg

[ Melting Point ]:
230-233 °C(lit.)

[ Molecular Formula ]:
C25H36Cl2N2O3

[ Molecular Weight ]:
483.471

[ Flash Point ]:
287.8ºC

[ Exact Mass ]:
482.210297

[ PSA ]:
42.01000

[ LogP ]:
5.94320

[ Vapour Pressure ]:
3.05E-12mmHg at 25°C

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LL9000000
CHEMICAL NAME :
Fluoren-9-one, 2,7-bis(2-(diethylamino)ethoxy)-, dihydrochloride
CAS REGISTRY NUMBER :
27591-69-1
LAST UPDATED :
199606
DATA ITEMS CITED :
17
MOLECULAR FORMULA :
C25-H34-N2-O3.2Cl-H
MOLECULAR WEIGHT :
483.53
WISWESSER LINE NOTATION :
L B656 HVJ EO2N2&2 LO2N2&2 &GH 2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human
DOSE/DURATION :
4 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - anorexia (human) Gastrointestinal - hypermotility, diarrhea
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
852 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
244 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
145 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
53500 ug/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Behavioral - muscle contraction or spasticity Lungs, Thorax, or Respiration - dyspnea
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
150 mg/kg/5D-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
250 mg/kg
SEX/DURATION :
female 10 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetal death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
400 mg/kg
SEX/DURATION :
female 10 day(s) after conception
TOXIC EFFECTS :
Reproductive - Maternal Effects - other effects Reproductive - Effects on Embryo or Fetus - fetal death

MUTATION DATA

TYPE OF TEST :
DNA adduct
TEST SYSTEM :
Mammal - species unspecified Lymphocyte
DOSE/DURATION :
100 umol/L
REFERENCE :
FEBLAL FEBS Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1968- Volume(issue)/page/year: 28,5,1972 *** REVIEWS *** TOXICOLOGY REVIEW CRTXB2 CRC Critical Reviews in Toxicology. (CRC Press, Inc., 2000 Corporate Blvd., NW, Boca Raton, FL 33431) V.1- 1971- Volume(issue)/page/year: 2,159,1973

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H335-H351

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R20/21/22;R36/37/38;R40

[ Safety Phrases ]:
S7-S22-S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
LL9000000

[ HS Code ]:
2922509090

Synthetic Route

Precursor & DownStream

Precursor

  • Tilorone
  • 2-Diethylaminoethylchloride Hydrochloride
  • 2-(Diethylamino)ethanol
  • Isopropanol

DownStream

  • Tilorone
  • 2-[7-[2-(diethylamino)ethoxy]-9-oxofluoren-2-yl]oxyethyl-diethyl-methylazanium,iodide

Customs

[ HS Code ]: 2922509090

[ Summary ]:
2922509090. other amino-alcohol-phenols, amino-acid-phenols and other amino-compounds with oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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