9-Borabicyclo[3.3.1]nonane

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Names

[ CAS No. ]:
280-64-8

[ Name ]:
9-Borabicyclo[3.3.1]nonane

[Synonym ]:
9-borabicyclononane
9-Borabicyclo[3.3.1]nonane solution
9-Borabicyclo(3.3.1)nonane
9-borabicyclo[3,3,1]nonane
EINECS 206-000-9
9-Borabicyclo[3.3.1]nonane
9-Borabicyclo[3.3.1]nonane monomer
9-BBN-dimer
MFCD00074742
Borabicyclononane
9-BBN monomer

Chemical & Physical Properties

[ Density]:
0.894 g/mL at 25 °C

[ Boiling Point ]:
179.3±23.0 °C at 760 mmHg

[ Melting Point ]:
150 - 152ºC

[ Molecular Formula ]:
C₈H₁₅B

[ Molecular Weight ]:
122.016

[ Flash Point ]:
62.3±22.6 °C

[ Exact Mass ]:
122.126678

[ LogP ]:
2.36770

[ Vapour Pressure ]:
1.3±0.3 mmHg at 25°C

[ Storage condition ]:
Flammables area

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H260-H302-H319-H335-H351

[ Supplemental HS ]:
May form explosive peroxides.

[ Precautionary Statements ]:
P210-P231 + P232-P280-P370 + P378-P402 + P404-P403 + P235

[ Hazard Codes ]:
F:Flammable;Xi:Irritant;

[ Risk Phrases ]:
R11;R14/15;R36/37/38

[ Safety Phrases ]:
16-26-36/37/39-45-43-33-62-61-36/37-29-7/8-37/39

[ RIDADR ]:
UN 3399 4.3/PG 1

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
4.1

[ HS Code ]:
2902199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1,5-cyclooctadiene
9,9'-Bi(9-borabicyclo[3.3.1]nonane)
Di-methylsulfide borane
9-bromo-9-(dimethylsulfonio)-9-borabicyclo[3.3.1]nonan-9-uide
(1R,5S)-9-chloro-9-(dimethyl-l4-sulfanyl)-9l4-borabicyclo[3.3.1]nonane
Borane-tetrahydrofuran (1:1)
9-(di-tert-butylphosphanyl)-9-bora{3.3.1}bicyclononane
sodiumborohydride

DownStream

methyl 11-(9-borabicyclo[3.3.1]nonan-9-yl)undecanoate
Indane
9-METHOXY-9-BORABICYCLO[3.3.1]NONANE
9,9'-Oxybis(9-borabicyclo[3.3.1]nonane)
[(cyclopentyl)2POC6H3OP(cyclopentyl)2]Ni(formate)
(Z)-3-BROMOACRYLICACID
9-Borabicyclo[3.3.1]nonane,9-phenyl-
9-butyl-9-borabicyclo[3.3.1]nonane
9-pentyl-9-borobicyclononane

Customs

[ HS Code ]: 2902199090

[ Summary ]:
2902199090 other cyclanes, cyclenes and cyclotherpenes。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

Articles

Spectroscopic and microscopic investigation of gold nanoparticle formation: ligand and temperature effects on rate and particle size.

J. Am. Chem. Soc. 133(21) , 8179-90, (2011)

We report a spectroscopic and microscopic investigation of the synthesis of gold nanoparticles (AuNPs) with average sizes of less than 5 nm. The slow reduction and AuNP formation processes that occur ...

Synthesis of aryl/alkyl building blocks for dendrimer and hyperbranched polymer synthesis.

Org. Lett. 6 , 667-669, (2004)

Several useful aryl/alkyl building blocks for dendrimer and hyperbranched polymer synthesis were prepared by Suzuki-Miyaura cross-coupling reactions and iododesilylation reactions. The iododesilylatio...

Multicomponent Mannich reactions with boron enolates derived from diazo esters and 9-BBN.

Org. Lett. 13 , 2510, (2011)

Diazo esters, arylboranes, and carbamoyl imines undergo a 3-component Mannich condensation reaction. Catalyzed by Cu(II) salts, the reaction affords the corresponding isocyanate Mannich product: one t...

9-borabicyclo<3.3.1>nonane
9-phenyl-9-borabicyclo[3.3.1]nonane
9-Borabicyclo[3.3.1]nonane-9-propanol
9-(Isopropylsulfanyl)-9-borabicyclo[3.3.1]nonane
9-Borabicyclo[3.3.1]nonane, 9-(2-methylbutoxy)-
9-Borabicyclo[3.3.1]nonane-9-ol
9-BORABICYCLO[3.3.1]NONANE