2,8,9-trioxa-5-aza-1-borabicyclo[3.3.3]undecane

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Names

[ CAS No. ]:
283-56-7

[ Name ]:
2,8,9-trioxa-5-aza-1-borabicyclo[3.3.3]undecane

[Synonym ]:
2,2`-DIHYDROXY-4.4`-DIMETHOXY-5.5`-SULFONICACIDBENZOPHENONE
1-Phospha-2,8,9-trioxa-adamantan
Triethanolamine Borate
1,3,5-Cyclohexanetriyl phosphite
2,8,9-trioxa-5-aza-1-bora-bicyclo[3.3.3]undecane
2,8,9-Trioxa-1-phospha-adamantan
2,8,9-trioxa-1-phospha-adamantane
MFCD00003272
2,8,9-trioxa-5-aza-1-borabicyclo[3.3.3]undecane
2,2',2''-Nitrilotriethyl Borate
2,8,9-Trioxa-1-phosphadamantane
EINECS 206-003-5
2,8,9-trioxa-5-aza-1-borabicyklo[3.3.3]undecane
1-Phospha-2,8,9-trioxa-adamantin
2,2',2''-nitrilotriethylborate
1,5-Cyclohexanetriyl phosphite
triethanolamineboric acid ester

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
149.6±39.0 °C at 760 mmHg

[ Melting Point ]:
235-237ºC

[ Molecular Formula ]:
C6H12BNO3

[ Molecular Weight ]:
156.975

[ Flash Point ]:
44.3±27.1 °C

[ Exact Mass ]:
157.091019

[ PSA ]:
30.93000

[ Vapour Pressure ]:
4.0±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.466

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
YJ8968050
CHEMICAL NAME :
2,8,9-Trioxa-5-aza-1-borabicyclo(3.3.3)undecane
CAS REGISTRY NUMBER :
283-56-7
BEILSTEIN REFERENCE NO. :
0774536
LAST UPDATED :
199612
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C6-H12-B-N-O3
MOLECULAR WEIGHT :
157.00

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>100 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Gastrointestinal - changes in structure or function of salivary glands Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
EJMCA5 European Journal of Medicinal Chemistry--Chimie Therapeutique. (Editions Scientifiques Elsevier, 29 rue Buffon, F-75005, Paris, France) V.9- 1974- Volume(issue)/page/year: 13,207,1978 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M4554 No. of Facilities: 189 (estimated) No. of Industries: 10 No. of Occupations: 12 No. of Employees: 22352 (estimated) No. of Female Employees: 4735 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
YJ8968050

[ HS Code ]:
2934999090

Synthetic Route

Precursor & DownStream

Precursor

  • Triethanolamine
  • Boric acid
  • Water
  • metaboric acid

DownStream

  • chloromethylsilatrane
  • PERFLUORODIETHYL ETHER
  • perfluoro-n-methylmorpholine
  • ETHOXYSILATRANE
  • 1-vinylsilatrane
  • PHENYLSILATRANE
  • Methylsilatrane

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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An introduction to boron: history, sources, uses, and chemistry.

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Following a brief overview of the terrestrial distribution of boron in rocks, soil, and water, the history of the discovery, early utilization, and geologic origin of borate minerals is summarized. Mo...

Partial denaturation of small chromatin fragments: direct evidence for the radial distribution of nucleosomes in folded chromatin fibers.

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An improved method for immobilizing IgG antibodies on protein A-agarose.

J. Immunol. Methods 127(2) , 215-220, (1990)

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Related Compounds

  • 3,7,10-Trimethyl-2,8,9-trioxa-5-aza-1-borabicyclo[3.3.3]undecane
  • 2,8,9-Trioxa-5-aza-1-borabicyclo[3.3.3]undecane,3-(phenoxymethyl)
  • 4,6,11-trioxa-1-aza-5-borabicyclo[3.3.3]undecane-3,7-dione
  • 2,8,9-Trioxa-5-aza-1-germabicyclo(3.3.3)undecane, 1-ethenyl-
  • 5-(3,3,4,4,5,5,6,6,7,7,8,8-dodecafluoro-1-iodooctyl)-4,6,11-trioxa-1-aza-5-silabicyclo[3.3.3]undecane
  • 2,8,9-Trioxa-5-aza-1-silabicyclo[3.3.3]undecane, 3,7,10-trimethyl-1-(4-methylphenyl)-
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
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  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
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  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine