4-Amino-3-methylphenol

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Names

[ CAS No. ]:
2835-99-6

[ Name ]:
4-Amino-3-methylphenol

[Synonym ]:
2-methyl-4-hydroxy aniline
4-Amino-3-methylphenol
4-hydroxy-2-methylphenylamine
4-Amino-m-cresol
p-amino-m-methylphenol
p-Hydroxy-o-toluidine
4-Hydroxy-2-methylaniline
4-hydroxy-6-methylaniline
3-Methyl-4-aminophenol
4-Amino-Meta-Cresol
p-Amino-m-cresol
Phenol,4-amino-3-methyl
2-methyl-1-amino-4-hydroxybenzene
Phenol, 4-amino-3-methyl-
MFCD00007871
2-Amino-5-hydroxytoluene
m-CRESOL,4-AMINO
EINECS 220-621-2

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
286.7±28.0 °C at 760 mmHg

[ Melting Point ]:
176-179 °C(lit.)

[ Molecular Formula ]:
C7H9NO

[ Molecular Weight ]:
123.152

[ Flash Point ]:
127.2±24.0 °C

[ Exact Mass ]:
123.068413

[ PSA ]:
46.25000

[ LogP ]:
0.17

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.616

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GO6826000
CHEMICAL NAME :
m-Cresol, 4-amino-
CAS REGISTRY NUMBER :
2835-99-6
BEILSTEIN REFERENCE NO. :
2078803
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C7-H9-N-O
MOLECULAR WEIGHT :
123.17
WISWESSER LINE NOTATION :
ZR DQ B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
680 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 3,35,1978

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S37/39-S36/37/39

[ RIDADR ]:
UN3077

[ WGK Germany ]:
3

[ RTECS ]:
GO6826000

[ Packaging Group ]:
III

[ Hazard Class ]:
9

[ HS Code ]:
29222900

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • HA 01-0196
  • Phenol, 4-amino-3-methyl-, acetate (ester) (9CI)
  • 2-Nitrotoluene
  • 3-Methyl-4-(2-nitro-phenylazo)-phenol
  • sodium m-cresolate
  • m-Cresol
  • N-hydroxy-2-toluidine
  • Sulfuric acid
  • Copper sulfate pentahydrate
  • 5-amino-2-hydroxy-4-methyl-benzoic acid

DownStream

  • 4-(BENZYLOXY)-2-METHYLANILINE
  • 4-Fluoro-3-methylphenol
  • Pyrolin
  • 2-Methylcyclohexa-2,5-diene-1,4-dione
  • 4-Iodo-3-methylphenol
  • 1-acetyl-1H-indazol-5-yl acetate
  • 1H-Indazol-5-ol
  • Phenol,2-methyl-4-[2-(4-nitrophenyl)diazenyl]-
  • HA 01-0196
  • nsc345816

Customs

[ HS Code ]: 2922299090

[ Summary ]:
2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Distinct mechanisms of oxidative DNA damage by two metabolites of carcinogenic o-toluidine.

Arch. Biochem. Biophys. 372(1) , 97-106, (1999)

Mechanisms of DNA damage by metabolites of carcinogenic o-toluidine in the presence of metals were investigated by the DNA sequencing technique using (32)P-labeled human DNA fragments. 4-Amino-3-methy...

Biotransformation of 3-methyl-4-nitrophenol, a main product of the insecticide fenitrothion, by Aspergillus niger.

J. Agric. Food Chem. 53(16) , 6426-31, (2005)

Biotransformation of the environmental pollutant 3-methyl-4-nitrophenol (MNP), a newly characterized estrogenic chemical, and the primary breakdown product of the heavily used insecticide fenitrothion...

Recognition of sequence-information in synthetic copolymer chains by a conformationally-constrained tweezer molecule.

Faraday Discuss. 143 , 205-20; discussion 265-75, (2009)

A novel type of tweezer molecule containing electron-rich 2-pyrenyloxy arms has been designed to exploit intramolecular hydrogen bonding in stabilising a preferred conformation for supramolecular comp...


More Articles

Related Compounds

  • 4-amino-3-methylphenol hydrochloride
  • 4-Amino-3-fluoro-2-methylphenol
  • 4-Amino-3-chloro-5-methylphenol
  • 4-amino-3-ethyl-5-methylphenol
  • 4-amino-2,6-dibromo-3-methylphenol
  • 4-amino-3,6-bis[[5-[[4-chloro-6-[(o-tolyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulphophenyl]azo]-5-hydroxynaphthalene-2,7-disulphonic acid