5'-chloro-2'-hydroxy-4'-methylacetophenone

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Names

[ CAS No. ]:
28480-70-8

[ Name ]:
5'-chloro-2'-hydroxy-4'-methylacetophenone

[Synonym ]:
2-Acetyl-4-chloro-5-methylphenol
2-hydroxy-4-methyl-5-chloroacetophenone
MFCD00191920
2-hydroxy-5-chloro-4-methylacetophenone
4-Acetyl-2-chloro-5-hydroxytoluene
4-methyl-5-chloro-2-hydroxyacetophenone
5'-Chloro-2'-hydroxy-4'-methylacetophenone
5-chloro-4-methyl-2-hydroxyacetophenone

Chemical & Physical Properties

[ Density]:
1.25g/cm3

[ Boiling Point ]:
137 °C / 15mmHg

[ Melting Point ]:
70-73 °C(lit.)

[ Molecular Formula ]:
C9H9ClO2

[ Molecular Weight ]:
184.62000

[ Flash Point ]:
132.2ºC

[ Exact Mass ]:
184.02900

[ PSA ]:
37.30000

[ LogP ]:
2.55660

[ Vapour Pressure ]:
0.000889mmHg at 25°C

[ Index of Refraction ]:
1.562

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914700090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-chloro-3-methylphenyl acetate
  • 4-chloro-6-[1-(hydroxyamino)ethylidene]-3-methylcyclohexa-2,4-dien-1-one
  • 4-Chloro-3-methylphenol
  • Acetyl chloride
  • acetic acid
  • 4-chloro-2-isopropyl-5-methyl-anisole

DownStream

  • 6-CHLORO-4-HYDROXY-7-METHYLCOUMARIN
  • 4-chloro-6-[1-(hydroxyamino)ethylidene]-3-methylcyclohexa-2,4-dien-1-one

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Synthesis of some new 1,3,5-trisubstituted pyrazolines bearing benzene sulfonamide as anticancer and anti-inflammatory agents.

Bioorg. Med. Chem. Lett. 21(14) , 4301-5, (2011)

Thirteen new 2-pyrazoline derivatives bearing benzenesulfonamide moiety (2a-m) were synthesized by condensing appropriate chalcones with 4-hydrazinonbenzenesulfonamide hydrochloride and tested for ant...

A Highly Sensitive and Selective Spectrophotometric Determination of Vanadium (V) Using 6-Chloro-3-hydroxy-7-methyl-2-(2-thienyl)-4H-chromen-4-one. Agnihotri N, et al.

Anal. Sci. 15(12) , 1261-64, (1999)

Pyridinium iodochloride: An efficient reagent for iodination of hydroxylated aromatic ketones and aldehydes. Khansole SV, et al.

J. Chin. Chem. Soc. 55(4) , 871-74, (2008)


More Articles

Related Compounds

  • 5'-CHLORO-2'-HYDROXY-4'-METHYL-3'-NITROACETOPHENONE
  • 5'-chloro-2'-hydroxy-4'-nitrobenzanilide
  • 4-tert-Butyl-5'-chloro-2'-hydroxy-4'-nitrobenzanilide
  • 1-(3-chloro-6-hydroxy-2,4-dimethoxyphenyl)ethanone
  • 5-chloro-2-hydroxy-4-methylbenzophenone
  • 5'-Chloro-2'-hydroxy-3-biphenylcarboxylic acid
  • 7-Fluoro-6-[(2-methoxyethyl)amino]-2-methyl-3,4-dihydroquinazolin-4-one
  • 6-[(Butan-2-yl)amino]-7-fluoro-2-methyl-3,4-dihydroquinazolin-4-one
  • 2-[4-Cyano-3-(trifluoromethyl)phenyl]-2-oxoacetic acid
  • 3-{[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-iodophenyl]formamido}propanoic acid
  • 2-[7-Fluoro-2-methyl-4-oxo-6-(propan-2-yloxy)-3,4-dihydroquinazolin-3-yl]acetic acid
  • tert-butyl 5-(morpholin-2-yl)-1H-1,2,3-triazole-4-carboxylate
  • tert-butyl 5-(1H-1,2,4-triazol-3-yl)-1H-1,2,3-triazole-4-carboxylate
  • N-{8-azaspiro[4.5]decan-1-yl}cyclobutanecarboxamide
  • 5-bromo-2-[4-(3,4-dimethoxyphenyl)-1H-1,2,3-triazol-1-yl]pyrimidine
  • 5-({5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]oxolan-2-yl}formamido)hexanoic acid
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