dibutylarsinic acid

Names

[ CAS No. ]:
2850-61-5

[ Name ]:
dibutylarsinic acid

[Synonym ]:
Di-n-butyl-arsinsaeure
Dibutyl-arsinsaeure
Arsinic acid,dibutyl
dibutyl-arsinic acid
ARSINE OXIDE,DIBUTYLHYDROXY

Chemical & Physical Properties

[ Boiling Point ]:
322.5ºC at 760mmHg

[ Molecular Formula ]:
C8H19AsO2

[ Molecular Weight ]:
222.15700

[ Flash Point ]:
152ºC

[ Exact Mass ]:
222.06000

[ PSA ]:
37.30000

[ LogP ]:
2.45160

[ Vapour Pressure ]:
2.21E-05mmHg at 25°C

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CH7280000
CHEMICAL NAME :
Arsine oxide, dibutylhydroxy-
CAS REGISTRY NUMBER :
2850-61-5
BEILSTEIN REFERENCE NO. :
1757626
LAST UPDATED :
199612
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C8-H19-As-O2
MOLECULAR WEIGHT :
222.19
WISWESSER LINE NOTATION :
Q-AS-O&4&4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
18 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01190 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994

Synthetic Route

Precursor & DownStream

Precursor

  • 1-Bromobutane
  • butyl(dichloro)arsane

DownStream

  • 6-Hexanolactone
  • 1-[butyl(ethoxy)arsoryl]butane
  • 1-dibutylarsoryloxybutane

Related Compounds

  • Thiovaleric acid S-sec-butyl ester
  • Octanethioic acid S-propyl ester
  • Hexanethioic acid S-decyl ester
  • Thiopropionic acid S-undecyl ester
  • trisporic acid
  • Benzoic acid, 3,4-dihydroxy-, 2-Methylpropyl ester
  • 2-[1-(3-Cyclohexylpropyl)piperidin-4-ylamino]-5-methylpyridine
  • Benzyl 1-(2-oxoethyl)cyclohexanecarboxylate
  • 2-[1-(4-Cyclohexylbutyl)piperidin-4-ylamino]-5-methylpyridine
  • Benzyl 1-allylcyclohexanecarboxylate
  • 2-{[(Tert-butoxy)carbonyl](oxan-4-yl)amino}acetic acid
  • Dimethyl 3-[1-(2-hydroxyethyl)cyclohexyl]-1,1-propanedicarboxylate
  • Dimethyl 2-(1-methoxycarbonylmethylcyclohexyl)malonate
  • [5-(2-Methyl-1,3-dioxolan-2-yl)thien-2-yl]methanol
  • Tetramethylthiouronium iodide,S-(2,4-dichlorophe
  • Benzyl (3-fluoro-4-(thietan-3-yl)phenyl)carbamate
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