Bromo(trimethyl)silane

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Names

[ CAS No. ]:
2857-97-8

[ Name ]:
Bromo(trimethyl)silane

[Synonym ]:
Silane, bromotrimethyl-
Bromotrimethylsilane,AcroSeal
Silane,bromotrimethyl
BroMotriMethylsilane
Bromo(trimethyl)silane
TMBS
Me3SiBr
Bromotrimethylsilane,Stab. With Copper Powder or Silver Wire
Trimethylbromosilane
Trimethylsilicon bromide
Trimethylsilyl bromide
MFCD00000048
EINECS 220-672-0
trimethylsilylbromide
tmsbr

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
79.0±0.0 °C at 760 mmHg

[ Melting Point ]:
-43 °C

[ Molecular Formula ]:
C3H9BrSi

[ Molecular Weight ]:
153.093

[ Flash Point ]:
-11.1±13.4 °C

[ Exact Mass ]:
151.965683

[ LogP ]:
2.34

[ Vapour Pressure ]:
100.3±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.424

[ Storage condition ]:
2-8°C

[ Stability ]:
Stable. Flammable. Incompatible with strong acids, strong oxidizing agents. May decompose on exposure to water or moist air.

[ Water Solubility ]:
DECOMPOSES

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R10;R14;R29;R34

[ Safety Phrases ]:
S16-S26-S36/37/39-S45-S8

[ RIDADR ]:
UN 2920 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2933990090

Synthetic Route

Precursor & DownStream

Precursor

  • Hexamethyldisilane
  • Hexamethyldisiloxane
  • Ethyl (trimethylsilyl)acetate
  • Trimethyl(vinyloxy)silane
  • trimethyl(phenylseleno)silane
  • Tris(Trimethylsilyl) Phosphate
  • Bis(trimethylsilyl) sulfate
  • bis(trimethylsilyloxymethyl)phosphorylmethoxy-trimethylsilane
  • trimethylsilyl tribromoacetate
  • N-(p-methoxybenzylidene)-p-toluidine

DownStream

  • 2-bromo-5,5-dimethyl-1,3,2-dioxaphosphinane
  • N,N-Diethyl-1,1,1-trimethylsilanamine
  • 1-bromoethyl phenyl carbonate
  • trimethyl(3-tritert-butylstannylprop-1-ynyl)silane
  • dimethyl trimethylsilyl phosphite
  • [bis(trimethylsilyl)]selenide
  • Tetrakis(trimethylsilyl) orthosilicate
  • trimethyl(1,2,2-trifluoroethenyl)silane
  • Hexamethyldisiloxane
  • Bromo(dimethyl)sulfonium bromide

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

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Related Compounds

  • bromo[10-[(trimethylsilyl)oxy]decyl]magnesium
  • bromo(trimethyl)arsanium,bromide
  • ethylsulfanylmethyl(trimethyl)silane
  • isocyano(trimethyl)silane
  • methanidyl(trimethyl)silane,vanadium
  • dimethoxyphosphoryl-trimethyl-silane