2-Methyl-3-furanthiol

Suppliers

Names

[ CAS No. ]:
28588-74-1

[ Name ]:
2-Methyl-3-furanthiol

[Synonym ]:
FEMA No. 3188
MFCD00010280
2-Methyl-3-furylthiol
2-Methyl-3-Mercaptofuran
3-Furanthiol, 2-methyl-
2-Methyl-3-furylmercaptan
2-methyl-furan-3-thiol
2-Methyl-3-furanethiol,balance oxidized compound
EINECS 249-094-7
2-methylfuran-3-thiol
3-mercapto-2-methylfuran
2-Methyl-3-furanthiol
2-methyl-3-sulfanylfuran
3-FURANTHIOL,2-METHYL

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
146.7±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C5H6OS

[ Molecular Weight ]:
114.165

[ Flash Point ]:
42.5±21.8 °C

[ Exact Mass ]:
114.013931

[ PSA ]:
51.94000

[ LogP ]:
2.14

[ Vapour density ]:
>1 (vs air)

[ Vapour Pressure ]:
5.8±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.536

[ Storage condition ]:
Freezer (-20°C)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LU6235000
CHEMICAL NAME :
3-Furanthiol, 2-methyl-
CAS REGISTRY NUMBER :
28588-74-1
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C5-H6-O-S
MOLECULAR WEIGHT :
114.17
WISWESSER LINE NOTATION :
T5OJ B1 CSH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DCTODJ Drug and Chemical Toxicology. (Marcel Dekker, 270 Madison Ave., New York, NY 10016) V.1- 1977/78- Volume(issue)/page/year: 3,249,1980

Safety Information

[ Symbol ]:

GHS02, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H301

[ Precautionary Statements ]:
P301 + P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T+:Verytoxic;

[ Risk Phrases ]:
R10;R25;R26;R36

[ Safety Phrases ]:
S16-S45-S39-S38-S28-S26

[ RIDADR ]:
UN 1228 3/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
LU6235000

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2932190090

Synthetic Route

Precursor & DownStream

Precursor

  • D-(+)-Xylose
  • Vitamin B1
  • L-cysteine
  • Fructose
  • Glutathione
  • D-(+)-Glucose
  • Glycolaldehyde
  • 1-mercapto-2-propanone

DownStream

  • Bis(2-methyl-3-furyl)disulfide
  • 3-(cyclohexyldisulfanyl)-2-methylfuran

Customs

[ HS Code ]: 2932190090

[ Summary ]:
2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

2-Methyl-3-furanthiol and methional are possible off-flavors in stored orange juice: aroma-similarity, NIF/SNIF GC-O, and GC analyses.

J. Agric. Food Chem. 49(11) , 5425-32, (2001)

The occurrence of methional in fresh orange juice, and possible occurrence of beta-damascenone in heated orange juice, has been previously suggested. Here we report on the occurrence of 2-methyl-3-fur...

Identification and origin of odorous sulfur compounds in cooked ham.

Food Chem. 155 , 207-13, (2014)

The aim of this work was to identify and gain further knowledge on the origin of sulfur compounds present in the volatile fraction of cooked ham, and on their role in the aroma of this product. To thi...

Effect of added thiamine on the key odorant compounds and aroma of cooked ham.

Food Chem. 173 , 790-5, (2015)

This study shows that thiamine plays a major role in the formation of three key odorants of cooked ham: 2-methyl-3-furanthiol, 2-methyl-3-methyldithiofuran, and bis(2-methyl-3-furyl)disulphide. Analys...


More Articles


Related Compounds

  • 2-methyl-3-furanthiol
  • 2-Methyl-3-furanthiol acetate
  • Tetrahydro-2-methyl-3-furanthiol
  • 2-Methyl-4,5-dihydro-3-furanthiol
  • 2-methyl-3-[(5-phenyl-1,3,4-oxadiazol-2-yl)methyl]quinazolin-4-one
  • 2-methyl-3,4-dihydro-1H-isoquinolin-7-ol
  • 1-(Piperazine-1-sulfonyl)azetidin-3-ol
  • 4-(3-Hydroxyazetidin-1-yl)thiophene-2-carbaldehyde
  • 2-Fluoro-6-(3-hydroxyazetidin-1-yl)benzaldehyde
  • 4-(3-Hydroxy-3-methylazetidin-1-yl)-2-methylbenzaldehyde
  • 5-Fluoro-2-(3-hydroxy-3-methylazetidin-1-yl)benzaldehyde
  • 5-(3-Hydroxy-3-methylazetidin-1-yl)-1,3-dimethyl-1H-pyrazole-4-carbaldehyde
  • tert-butyl (2S,5S)-2-methyl-5-propan-2-ylpiperazine-1-carboxylate
  • 1-(6-Methoxypyridin-3-yl)cyclopropan-1-ol
  • 1-(5-Methyl-1,2-oxazol-3-yl)cyclopropan-1-ol
  • 1-(4-Fluoro-3-nitrophenyl)cyclopropan-1-ol
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