ETHYL ALPHA-BROMOPHENYLACETATE

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Names

[ CAS No. ]:
2882-19-1

[ Name ]:
ETHYL ALPHA-BROMOPHENYLACETATE

[Synonym ]:
ethyl-2-bromo-2-phenylacetate
ETHYL A-BROMOPHENYLACETATE
ethyl 2-phenyl-2-bromoacetate
MFCD00013536
ETHYL 2-BROMOPHENYLACETATE
Ethyl alpha-bromophenylacetate
Einecs 220-735-2
(+/-)-2-bromo-2-phenylacetic acid ethyl ester
Ethyl 2-bromo-2-phenylacetate
ethyl bromo-phenylacetate

Chemical & Physical Properties

[ Density]:
1.389 g/mL at 25 °C(lit.)

[ Boiling Point ]:
89-92 °C0.9 mm Hg(lit.)

[ Molecular Formula ]:
C10H11BrO2

[ Molecular Weight ]:
243.09700

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
241.99400

[ PSA ]:
26.30000

[ LogP ]:
2.68570

[ Vapour Pressure ]:
0.00368mmHg at 25°C

[ Index of Refraction ]:
n20/D >1.5390(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

Precursor & DownStream

Precursor

  • 2-Bromo-2-phenylacetic acid
  • Ethanol
  • Ethyl phenylacetate
  • ethyl mandelate
  • Ethyl 3-oxo-4-phenylbutanoate
  • ethyl 2-bromo-2-(cyclohexa-2,5-dienyl)acetate
  • ALPHA-BROMOPHENYLACETYL CHLORIDE
  • Phenylacetyl chloride
  • ethyl 2-bromoacetate
  • Phenylboronic acid

DownStream

  • 3-phenylpiperazin-2-one
  • Tropic acid
  • Phenylacetic acid
  • Benzeneacetic acid, a,a'-thiobis-
  • alpha-Sulfophenylacetic acid
  • 2(3H)-Furanone,dihydro-3,5,5-triphenyl-
  • 3-hydroxy-2-methyl-4-phenyl-2H-furan-5-one
  • Benzenebutanoic acid, b-oxo-a-phenyl-, ethyl ester
  • Ethyl phenylacetate
  • 3-phenyl-3,4-dihydro-1H-quinoxalin-2-one

Articles

Diffusion-regulated phase-transfer catalysis for atom transfer radical polymerization of methyl methacrylate in an aqueous/organic biphasic system.

Macromol. Rapid Commun. 36(6) , 538-46, (2015)

A concept based on diffusion-regulated phase-transfer catalysis (DRPTC) in an aqueous-organic biphasic system with copper-mediated initiators for continuous activator regeneration is successfully deve...

Control of a living radical polymerization of methacrylates by light.

Angew. Chem. Int. Ed. Engl. 51(35) , 8850-3, (2012)

Activators regenerated by electron transfer for atom-transfer radical polymerization of (meth)acrylates and related block copolymers.

Angew. Chem. Int. Ed. Engl. 45(27) , 4482-6, (2006)


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Related Compounds

  • METHYL ALPHA-BROMOPHENYLACETATE
  • Methyl alpha-bromophenylacetate
  • ethyl alpha-cyanodecahydro-4,8,8-trimethyl-1,4-methanoazulene-9-propionate
  • α-Iodophenylacetic Acid Ethyl Ester , 2-Iodo-2-phenylacetic Acid Ethyl Ester , Ethyl2-Iodo-2-phenylacetate
  • ethyl alpha-((3-(2-hydroxy-2-oxoethoxy)phenyl)methyl)-4,5-diphenyl-2-oxazoleacetate
  • ethyl alpha-cyclohexyl-alpha-hydroxythiophen-2-acetate