Dimethyl chloromalonate

Suppliers

Names

[ CAS No. ]:
28868-76-0

[ Name ]:
Dimethyl chloromalonate

[Synonym ]:
Dimethyl chloromalonate
CHCl(CO2Me)2
2-Chloro-malonic acid dimethyl ester
dimethyl chloropropanedioate
EINECS 249-275-0
dimethyl 2-chloromalonate
Propanedioic acid, 2-chloro-, dimethyl ester
MFCD00042837
2-chlorodimethylmalonate

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
215.4±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C5H7ClO4

[ Molecular Weight ]:
166.560

[ Flash Point ]:
106.7±0.0 °C

[ Exact Mass ]:
166.003281

[ PSA ]:
52.60000

[ LogP ]:
0.24

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.431

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Dimethyl malonate
  • tetramethylethylene
  • Dimethyl but-2-ynedioate

DownStream

  • (4-Methylphenyl)methanesulfonyl chloride
  • 2-Phenylethanesulfonyl chloride
  • Dimethyl fluoromalonate
  • 1,1,2,2-Ethenetetracarboxylicacid, 1,1,2,2-tetramethyl ester
  • dimethyl 2,2-dimethoxypropanedioate
  • 4-n-propylbenzenesulfonyl chloride
  • 1,1,2,2-Ethanetetracarboxylic acid, tetramethyl ester
  • dimethyl 2,2-dichloropropanedioate

Articles

Stereoselective synthesis of highly functionalized nitrocyclopropanes via organocatalyic conjugate addition to nitroalkenes.

J. Org. Chem. 71(19) , 7494-7, (2006)

A convenient and novel one-pot organocatalytic methodology for the stereoselective synthesis of highly functionalized nitrocyclopropanes is reported. The addition of dimethyl chloromalonate to a varie...

A preparative method for Synthesis of 4, 5, 6-trichloropyrimidine. Ostrowski S, et al.

ARKIVOC 6 , 905-8, (2000)

New one-pot synthesis of tetra-alkoxycarbonylallylidenetriphenylphosphoranes. Yavari I and Baharfar R.

Tetrahedron Lett. 39(9) , 1051-54, (1998)


More Articles

Related Compounds

  • dimethyl-bis(2-methylpropyl)azanium,iodide
  • [dimethyl(phenyl)-λ5-arsanyl] thiohypobromite
  • [dimethyl(phenyl)-λ5-arsanyl] thiohypochlorite
  • dimethyl glutarate
  • Dimethyl 3-hydroxypentanedioate
  • dimethyl 7,7-dimethoxybicyclo<2.2.1>hept-5-ene-2,3-dicarboxylate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine