2-Bromosulfonyl chloride

Suppliers

Names

[ Name ]:
2-Bromosulfonyl chloride

[Synonym ]:
2-Bromobenzenesulfonyl chloride
bromophenylsulfonyl chloride
Benzene, 1-bromo-2-chlorosulfonyl-
Benzenesulfonyl chloride, 2-bromo-
Benzenesulfonyl chloride,2-bromo
O-BROMOBENZENESULFONYL CHLORIDE
MFCD00051971
2-Bromobenzenesulphonyl chloride
2-bromobeneze sulfonyl chloride
bromobenzenesulfonyl chloride
2-Bromobenzene-1-sulfonyl chloride
2-Bromosulfonyl chloride
2-Bromophenylsulfonyl chloride
2-Bromobenzenesulfonylchloride
2-Bromobenzenesulfonyl

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
312.4±25.0 °C at 760 mmHg

[ Melting Point ]:
49-52 °C(lit.)

[ Molecular Formula ]:
C₆H₄BrClO₂S

[ Molecular Weight ]:
255.517

[ Flash Point ]:
142.7±23.2 °C

[ Exact Mass ]:
253.880386

[ PSA ]:
42.52000

[ LogP ]:
2.52

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.592

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S27-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2904909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

2'-SULFAMOYL-BIPHENYL-4-CARBOXYLICACID
2-Phenylpiperidine
2-Bromobenzenesulfonamide
N-Isopropyl 2-bromobenzenesulfonamide
3-Phenylpyrrolidine
1-((2-BROMOPHENYL)SULFONYL)PYRROLIDINE
2-Bromo-N-propylbenzenesulfonamide
4-Chloro-N-methylaniline
2-Bromo-N-methylbenzenesulfonamide
2-Bromo-N,N-diethylbenzenesulphonamide

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Palladium-Catalysed Intramolecular Direct Arylation of 2-Bromobenzenesulfonic Acid Derivatives. Bheeter C, et al.

Adv. Synth. Catal. 354(18) , 3533-38, (2012)

Solid-phase synthesis of acyl biarylsulfonamides. Xiong Y, et al.

Tetrahedron Lett. 42(48) , 8423-27, (2001)

Chiral sulfoxide ligands bearing nitrogen atoms as stereocontrollable coordinating elements in palladium-catalyzed asymmetric allylic alkylations. Hiroi K, et al.

Tetrahedron Asymmetry 9(21) , 3797-3817, (1998)

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