Methyl 2-hydroxy-5-methoxybenzoate

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Names

[ CAS No. ]:
2905-82-0

[ Name ]:
Methyl 2-hydroxy-5-methoxybenzoate

[Synonym ]:
Methyl 2-hydroxy-5-methoxybenzoate
Methyl 5-Methoxysalicylate
methyl 5-methoxy-2-hydroxybenzoate
methyl 2-hydroxy-5-methoxy benzoate
MFCD00017185
Benzoic acid, 2-hydroxy-5-methoxy-, methyl ester
2-Hydroxy-5-methoxybenzoic Acid Methyl Ester
5-Methoxysalicylic Acid
5-Methoxysalicylic Acid Methyl Ester

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
280.3±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C9H10O4

[ Molecular Weight ]:
182.173

[ Flash Point ]:
109.8±15.3 °C

[ Exact Mass ]:
182.057907

[ PSA ]:
55.76000

[ LogP ]:
2.03

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.534

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2918990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 5-Methoxysalicylic Acid
  • methyl iodide
  • Methyl2,5-dihydroxybenzoate
  • Methanol
  • Gentisic acid
  • Dimethyl sulfate
  • methyl 2-(methoxycarbonyl)-4-methoxyphenyl phosphate
  • Sodium Methylate
  • diazomethane

DownStream

  • 1-Hydroxy-2,3,4,7-tetramethoxyxanthone
  • 2-(2-Hydroxy-2-propyl)-4-methoxyphenol
  • 2H-1-BENZOPYRAN-2-ONE, 4-HYDROXY-6-METHOXY-3-METHYL-
  • 2-HYDROXY-5-METHOXYBENZHYDRAZIDE
  • 2-hydroxy-5-methoxybenzamide
  • methyl 3-bromo-2-hydroxy-5-methoxybenzoate
  • METHYL 2-HYDROXY-5-METHOXY-3-NITROBENZENECARBOXYLATE
  • methyl 5-methoxy-2-(trifluoromethylsulfonyloxy)benzoate
  • Benzoic acid,2-mercapto-5-methoxy-
  • 9H-XANTHEN-9-ONE, 2-METHOXY-

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Excited state proton transfer: A new feature in the fluorescence of methyl 5-chlorosalicylate and methyl 5-methoxysalicylate. Acuña AU, et al.

J. Photochem. 30(3) , 339-52, (1985)

One-pot synthesis of xanthones and thioxanthones by the tandem coupling-cyclization of arynes and salicylates. Zhao J and Larock RC.

Org. Lett. 7(19) , 4273-75, (2005)

Photoinduced intramolecular proton transfer in methyl salicylates: a theoretical study with spectroscopic support. Sanchez-Cabezudo M, et al.

J. Mol. Struct. 131(3) , 277, (1985)


More Articles

Related Compounds

  • Methyl 2-hydroxy-5-iodo-4-methoxybenzoate
  • methyl 2-hydroxy-5-(4-hydroxy-2-methoxy-5-methoxycarbonyl-phenyl)sulfonyl-4-methoxy-benzoate
  • methyl 2-hydroxy-5-[1-hydroxy-2-(4-phenylbutan-2-ylamino)ethyl]benzoate
  • methyl 2-hydroxy-5-iodocyclohex-3-ene-1-carboxylate
  • Methyl 2-hydroxy-5-iodonicotinate
  • Methyl 2-hydroxy-5-iodobenzoate
  • N-(2-ethoxyphenyl)-2-((1-ethyl-6-(furan-2-ylmethyl)-3-methyl-7-oxo-6,7-dihydro-1H-pyrazolo[4,3-d]pyrimidin-5-yl)thio)acetamide
  • 2-((1-ethyl-6-(furan-2-ylmethyl)-3-methyl-7-oxo-6,7-dihydro-1H-pyrazolo[4,3-d]pyrimidin-5-yl)thio)-N-(4-methoxybenzyl)acetamide
  • N-[(4-chlorophenyl)methyl]-2-({1-ethyl-6-[(furan-2-yl)methyl]-3-methyl-7-oxo-1H,6H,7H-pyrazolo[4,3-d]pyrimidin-5-yl}sulfanyl)acetamide
  • N-(benzo[d][1,3]dioxol-5-yl)-2-((1-ethyl-6-(furan-2-ylmethyl)-3-methyl-7-oxo-6,7-dihydro-1H-pyrazolo[4,3-d]pyrimidin-5-yl)thio)acetamide
  • N-(2,3-dimethylphenyl)-2-((1-ethyl-6-(furan-2-ylmethyl)-3-methyl-7-oxo-6,7-dihydro-1H-pyrazolo[4,3-d]pyrimidin-5-yl)thio)acetamide
  • 1-ethyl-6-[(furan-2-yl)methyl]-3-methyl-5-({[3-(trifluoromethyl)phenyl]methyl}sulfanyl)-1H,6H,7H-pyrazolo[4,3-d]pyrimidin-7-one
  • 2-((1-ethyl-3-methyl-7-oxo-6-(thiophen-2-ylmethyl)-6,7-dihydro-1H-pyrazolo[4,3-d]pyrimidin-5-yl)thio)-N-(3-methoxyphenyl)acetamide
  • N-(2-chlorophenyl)-2-((1-ethyl-3-methyl-7-oxo-6-(thiophen-2-ylmethyl)-6,7-dihydro-1H-pyrazolo[4,3-d]pyrimidin-5-yl)thio)acetamide
  • 2-((1-ethyl-3-methyl-7-oxo-6-(thiophen-2-ylmethyl)-6,7-dihydro-1H-pyrazolo[4,3-d]pyrimidin-5-yl)thio)-N-(4-isopropylphenyl)acetamide
  • 2-({1-ethyl-3-methyl-7-oxo-6-[(thiophen-2-yl)methyl]-1H,6H,7H-pyrazolo[4,3-d]pyrimidin-5-yl}sulfanyl)-N-phenylacetamide
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