Diethyl bromo(methyl)malonate

Suppliers

Names

[ Name ]:
Diethyl bromo(methyl)malonate

[Synonym ]:
2-bromo-2-methylmalonic acid diethyl ester
Br(Me)C(COOEt)2
diethyl 2-bromo-2-methyl malonate
EINECS 249-541-6
Diethyl bromo(methyl)malonate
Diethyl bromomethylmalonate
Propanedioic acid, 2-bromo-2-methyl-, diethyl ester
Propanedioic acid, bromomethyl-, diethyl ester
Diethyl 2-Bromo-2-methylmalonate
Br(CH3)C(COOEt)2
MFCD00009125

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
238.0±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C₈H₁₃BrO₄

[ Molecular Weight ]:
253.090

[ Flash Point ]:
97.8±21.8 °C

[ Exact Mass ]:
251.999710

[ PSA ]:
52.60000

[ LogP ]:
2.33

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.469

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R20/21/22;R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2917190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Ethyl methylmalonate
ETHYL 2-METHYL-7-NITRO-3-OXO-3,4-DIHYDRO-2H-1,4-BENZOXAZINE-2-CARBOXYLATE
2-(Octylthio)pyridine
1-Bromooctane
Ethyl 3,4-dihydro-2-methyl-6-nitro-3-oxo-2H-1,4-benzoxazine-2-carboxylate
diethyl 2-methyl-2-phenacylpropanedioate
diethyl 2-but-3-en-2-yl-2-methylpropanedioate
Diethyl methyl(3-oxocyclohexyl)malonate

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Controlled/“living” atom transfer radical polymerization of methyl methacrylate using various initiation systems. Matyjaszewski K, et al.

Macromolecules 31(5) , 1527-1534, (1998)

Organic reducing agents. Reduction of electron deficient bromides by 1, 2, 2, 6, 6-pentamethylpiperidine (PMP)/mercaptoethanol. Amoli M, et al.

Tetrahedron Lett. 36(23) , 3997-4000, (1995)

TAILOR MADE POLYMERIC SYSTEMATIC LIBRARIES VIA ATOM TRANSFER RADICAL POLYMERIZATION. Jakubowski W, et al.

Polymer Prepr. 49(2) , 369, (2008)

diethyl 2-(2-(bromo-methyl)benzylidene)malonate
diethyl {[(4-bromo-3-ethoxyphenyl)amino]methyl}malonate
diethyl 2-acetamido-2-((5-bromo-1-(phenylsulfonyl)-1H-indol-3-yl)methyl)malonate
Diethyl methyl(phenyl)malonate
diethyl (bromo(1,3-dithiolan-2-ylidene)methyl)phosphonate
Diethyl methyl(3-oxocyclohexyl)malonate
2-Ethynyl-4,6-difluoro-1,3-benzothiazole
rac-N-{[(3aR,6aR)-octahydrocyclopenta[b]pyrrol-3a-yl]methyl}ethane-1-sulfonamide
2-Ethynyl-6-(methylthio)benzo[d]thiazole
5-(5-bromopyridin-2-yl)-1H-imidazol-2-amine
3-{2-Aminobicyclo[2.2.2]octan-2-yl}azetidin-3-ol
4-(5-chloro-2-ethylcyclohexyl)-1-methyl-1H-1,2,3-triazole
6a-Fluoro-2-nitroso-octahydrocyclopenta[c]pyrrole-3a-carboxylic acid
3-(2-Amino-2,3,3-trimethylbutyl)-1-propylurea
1-(2-{[(Tert-butoxy)carbonyl]amino}-4-methyl-1,3-thiazol-5-yl)cyclobutane-1-carboxylic acid
3-Amino-2-(2-{[(tert-butoxy)carbonyl]amino}-4-methyl-1,3-thiazol-5-yl)propanoic acid

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