Chloro(tert-butyl)phenylphosphine

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Names

[ CAS No. ]:
29949-69-7

[ Name ]:
Chloro(tert-butyl)phenylphosphine

[Synonym ]:
tert-BuPhPCl
tert-butylphenylphosphine chloride
tert-Butylphenylchlorophosphine

Chemical & Physical Properties

[ Density]:
1.064 g/mL at 25 °C

[ Boiling Point ]:
228ºC at 760mmHg

[ Molecular Formula ]:
C10H14ClP

[ Molecular Weight ]:
200.64500

[ Flash Point ]:
91.7ºC

[ Exact Mass ]:
200.05200

[ PSA ]:
13.59000

[ LogP ]:
3.74610

[ Appearance of Characters ]:
liquid | colorless

[ Vapour Pressure ]:
0.113mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.555

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
10-14-34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 2920 8/PG 2

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • tert-butyl chloride
  • Dichlorophenylphosphine
  • TERT-BUTYLMAGNESIUM CHLORIDE
  • Tert-Butyllithium
  • chloro-phenyl-sulfanylidene-tert-butyl-phosphorane
  • magnesium,2-methylpropane,bromide
  • [tert-butyl(chloro)phosphoryl]benzene

DownStream

  • tert-butyl-ethenyl-phenylphosphane
  • t-Butylphenylphosphine
  • Chlorotrimethylsilane
  • 1-(tert-butyl(phenyl)phosphanyl)-1H-imidazole

Related Compounds

  • chloro(tert-butyl)diethylamino(methylene)phosphorane
  • 4-(chloro-tert-butyl)-benzoic acid
  • N-(chloro-tert-butyl)acrylamide
  • 1-chloro-tert-butyl alcohol
  • Bis(di-tert-butyl-phenylphosphine)palladium(0), Pd 19.3
  • 1-chloro-2-methyl-2-(4-nitrophenyl)propane
  • 3-{[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-1-methyl-1H-pyrazol-5-yl]formamido}pentanoic acid
  • 2-(2-{[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-1-methyl-1H-pyrazol-5-yl]formamido}ethoxy)acetic acid
  • 3-(1-Methoxycyclopentyl)-2,2-dimethylpropanal
  • 1-(1-Aminopropyl)-4-methylcyclohexan-1-ol
  • 7-Ethyl-5-(propan-2-yl)-1-oxa-4-azaspiro[5.5]undecane
  • (2S)-2-{[5-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-1-methyl-1H-pyrazol-4-yl]formamido}-4-methylpentanoic acid
  • (2S)-2-{[(1RS,2SR)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclohexyl]formamido}-3,3-dimethylbutanoic acid
  • (4R)-3-[(1RS,2SR)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclohexanecarbonyl]-1,3-thiazolidine-4-carboxylic acid
  • (2R)-2-[(3S)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylpentanamido]pentanoic acid
  • 1-[(3S)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylpentanoyl]-4-hydroxypiperidine-4-carboxylic acid
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