Isocrotyl bromide

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Names

[ CAS No. ]:
3017-69-4

[ Name ]:
Isocrotyl bromide

[Synonym ]:
Propene, 1-bromo-2-methyl-
1-Br-2-Me-1-propene
3-bromo-2-methyl-2-propene
1-bromo-2-methylprop-1-ene
1-Propene, 1-bromo-2-methyl-
2-methyl propenyl bromide
2-methyl-1-bromopropene
1-bromo-2-methylpropene
2-Methyl-1-propenyl bromide
β,β-Dimethylvinylbromide
Isocrotyl bromide
1-Bromo-2-methyl-1-propene
MFCD00009885

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
87.2±9.0 °C at 760 mmHg

[ Melting Point ]:
-115.07°C (estimate)

[ Molecular Formula ]:
C4H7Br

[ Molecular Weight ]:
135.002

[ Flash Point ]:
13.6±15.1 °C

[ Exact Mass ]:
133.973099

[ LogP ]:
2.68

[ Vapour Pressure ]:
72.4±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.470

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F: Flammable;Xi: Irritant;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
16-26-33

[ RIDADR ]:
UN 1993 3

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2903399090

Synthetic Route

Precursor & DownStream

Precursor

  • 1,2-Dibromo-2-methyl-propane
  • 3,3-Dimethylacrylic acid
  • 2,3-dibromo-3-methylbutanoic acid
  • Bromotrifluoromethane (R 13B1)
  • Bromo(isopropyl)magnesium
  • Pyridine
  • 2-Bromopropane
  • Ammonia
  • Ethanol
  • Trimethylamine

DownStream

  • 9-(2-methylprop-2-enylidene)fluorene
  • 3-Methyl-2-butenenitrile
  • (2-methyl-1-phenylpropan-2-yl)benzene
  • [(2R,3R)-3-phenylbutan-2-yl]benzene
  • Benzene,1,1'-(2-methylpropylidene)bis-
  • (1-methyl-2-phenylpropyl)benzene
  • 1-iodo-2-methylprop-1-ene
  • 3,3-Dimethylacrylic acid
  • Hexaphenylditin
  • (2-Methylallyl)triphenylstannane

Customs

[ HS Code ]: 2903399090

[ Summary ]:
2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Total synthesis of the ocular age pigment A2-E: a convergent pathway. Ren R X-F, et al.

J. Am. Chem. Soc. 119(15) , 3619-20, (1997)

Palladium-catalyzed conjugated diene synthesis from vinylic halides and olefinic compounds. Dieck HA and Heck RF.

J. Org. Chem. 40(8) , 1083-90, (1975)

Biosynthesis of iridoid monoterpenes in insects: Defensive secretions from larvae of leaf beetles (coleoptera: chrysomelidae). Veith M, et al.

Tetrahedron 50(23) , 6859-74, (1994)


More Articles


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